层状钙钛矿多铁材料的制备和性能研究凝聚态物理专业论文.docxVIP

三 三 扬州人学硕’}：学何论文 剩余磁化强度(2M0住掺杂量x=O．5时达到最大值，为2．3 memu／g，是未掺杂时的 1000倍，2M随掺杂量X的变化说明样品铁磁性的增强可能来源于Fe．O．Co耦合。 在不同Co含量下，BFCT-x样品都具有铁电性，但随掺杂量X的增加，剩余极化强 度(2B)呈现先增加，减小后又增加的趋势。当掺杂量x=0．1时，样品的铁电性能最 好，2Pr=11／．,C／cm2，比未掺杂时提高了38．2％。并且随着掺杂量X的增加，BFCT-x 样品的居罩温度略有降低，畸变逐渐变小，意味着铁电性的变化主要与B位离子排 列有序程度相关。实验得到综合性能最佳的Co掺杂样品为BFCT-0．5，在室温下能 同时具备良好的铁电和铁磁性能。这为磁电材料的进一步研究和可应用于实际生产 的多功能器件的制备提供了方便。 采用相同工艺用等价La3+离子对Bi5Ti3FeOl5进行了A位掺杂，制备了 Bi5．，、．La翔3FeOl5(BLFT-x，X=0．25、0．75)多铁陶瓷样品。实验发现A位La”离子掺 杂没有改变BFTO的基本结构，对样品的磁性能产生了微小的影响。当La掺杂量X =0．75时，磁滞回线中问出现了一个小鼓包，这可能是由于La”离子和Fe3+离子通 过02。离子产生的La．O．Fe间接耦合导致了样品中Fe．O．Fe耦合为倾斜的反铁磁交换 作用。但La掺杂对样品的铁电性能影响较大，La掺杂量X=O．25时，样品的铁电 性能最好，在外加电场150 kV／cm下剩余极化2Pf．=10．2,uC／cm2，是未掺杂时的四 倍。同时BLFT-x的介电常数和介电损耗随温度的变化表明样品的居罩温度Tc．随La 掺杂量z的增加而减小。 关键词：单相多铁材料，剩余极化，剩余磁化，介电常数，介电损耗 Abstract Abstract In recent years，a considerable amount of research has been done to search for the single-phase multiferroic materials which can exhibit both fine magnetic order and ferroelectricity(FE)order above room temperature．In present system,bismuth layer-structured single-phase magnetoelectric multiferroics is one of widely studied materials because of its good FE properties at room temperature(RT)．They are formed by inserting BiFe03(BFO)perovskite into the bismuth layer-structured ferroelectfics and still belong to a family of Aurivillius phase．The Bi202 layers in the materials playing roles of both space—charge compensation and insulating blocks Can reduce the high leakage current and make the compounds possess the good FE properties with the magnetic order．However,the magnetic nature of the materials at RT is still weak and requires improvement．Furthermore，reports about them mainly focus on the studies of the four—layered or higer—layered Aurivillius multiferroic compounds．Therefore，in this letter we时to prepare the two—layered and three-layered single—phase magnetoelectric multiferroics and modify properties of four-layered multiferroics Bi5Ti3FeOl 5(BFTO) which has best FE properties in this system by equ