废新闻纸中性脱墨的研究制浆造纸工程专业论文.docxVIP

摘 摘 要 论文用自制表面活性剂对废新闻纸的中性脱墨进行了研究，确定 了最佳中性脱墨工艺，筛选出了适合废新闻纸中性脱墨的单组分及多 组分脱墨用表面活性剂。同时对废新闻纸化学法中性脱曼和碱法脱墨 进行了比较，此外，还对中性脱墨过程中纸浆和油墨粒子的特性进行 了分析。 首先合成了一系列脱墨用非离予表面活性荆，并对其浊点、HLB 值及表面张力进行了表征，另外通过红外光谱分析对其结构进行了验 证。 在废新闻纸中性脱墨过程中，机械作用是影响最终脱墨浆效果的 主要因素，低浓、短时间和中高转速碎浆能有效提高中性脱黑的效率。 而碎浆前的预浸渍和碎浆后的适度保温是十分必要的。 实验得出了适合于废新闻纸中性脱墨的配方： 0．4％RPE-2-巾．2％Y4+3％WI；0．6％RPE-2+3％Wl：0．6％RPE-2 +3％W1+0．05EGU／g N342。 与传统的碱法脱墨相比，废新闻纸中性脱墨后油墨粒子的粒径稍 大，有利于浮选除去；废新闻纸的中性脱墨可以明显降低废水的CODc。 含量，减少了废水的污染负荷。与碱法脱墨浆相比，中性脱墨浆具有 更好的H202后续漂白效果，达到相同白度时，中性脱墨可以节约近 60％的H202用量。 显微镜观察和粒径分析表明，在中性脱墨的碎浆初期，纤维阊油 墨及外层油墨以较大尺寸和较高的脱除速率与纤维分离；碎浆中期， 内层油墨逐渐剥离，脱除速率下降，部分脱离的油墨发生碎化；碎浆 后期，油墨脱除量较少，主要为内层油墨的脱除，纤维表面较为洁净； 进一步延长碎浆时间，油墨出现回吸，过长的保温处理不利于油墨的 去除。 关键词：化学法中性脱墨碱法脱墨HLB值合成红外光谱污染负 荷漂白显微镜观察粒径分析 NEUTRAL NEUTRAL DE磷KING 0蕾OLD NEWSPRDqT Wang Shouquan Superadviser：Qin Meng—hua(Professor) Shandong Institute of Light Industry,Jinan，250100，ER．China ABSTRACT The neural deinking of old newsprint(ONP)using synthetical suffactants was investigated and the neu口al deinking technical parameters were optimized．Additionally,the single and multiplex sttffactants for chemical neu删deinking of ONP were selected．At the same time。the neutral deinking and alkaline deinking of ONP was compared and the deinkcd pulp properties and the characteristics of toner particles during neural deinking process were also analyzed． Several series of nonionic surfactants．as components of deinking agents for ONP recycling．wefe synthesized．Their turbid point,HLB value and surface tension were examined，and their structures were determined by IR spectral analysis． The results showed that the mechanical actions in the pulping were the main factors which affected the deinkcd pulp properties．Low-consistency, short-time and medium or high-rapid pulping could improve the deinking efficiency．In addition，impregnation before pulping and retention with a temperature after pulping were both necessary for increasing the deinked pulp properties． In this paper,the complexes of deinking agenm w∽obtained： 0．4％RPE．