端氨基超支化聚合物的制备及在皮革中的应用研究皮革化学与工程专业论文.docxVIP

中对坯革物理机械性能的影响，检测结果表明NH2．HBP的加入可以改善坯 中对坯革物理机械性能的影响，检测结果表明NH2．HBP的加入可以改善坯 革的增厚率和物理机械性能。 为了考察NH2．HBP的复鞣性能，将NH2．HBP应用在绵羊皮服装革复 鞣工艺中，研究将NH2．HBP作为复鞣剂对皮革复鞣性能的影响。结果表明， 将用量为6％的NH2．HBP在加脂之前加入对坯革的物理机械性能有明显提 高，平均Ts提高4．4℃，平均抗张强度由l 1．76N／mm2提高至15．94N／mm2， 提高了35．54％，平均撕裂强度由22．47N／mm提高至33．73N／mm，提高了 47．3 1％。同时检测在此工艺条件下，NH2．HBP的加入对皮革染色性能的影 响。结果显示NH2．HBP能提高皮革的染色性能，皮革上染率提高5．06％， 皮革染色废液透亮，颜色浅，皮革粒面颜色明显变深。 关键词：端氨基超支化聚合物，皮革，固色，除醛，复鞣 万方数据 PREPA PREPA R ATIoN OF AMINO．TERMD怆TED HYPERBR八NCHED PO删ERSAND ITS APPLICATION IN LEATHER ABSTRACT The preparation of amino-terminated hyperbranched polymers(NH2-HBP) was based on previous single—factor experiment results．111e optimal preparation process parameters of NH2一HBP were studied by orthogonal experiment．The NH2-HBP was applied in dyeing，formaldehyde．removal and retanning process of sheep skin garment leather to study its optimal application parameters in leather．The main research contents and results are as follows． The parameters optimization of NH2．HBP preparation process was carried out through orthogonal experiment，in which N，N—methylene bisacrylamide and diethylene triamine were used嬲raw materials．the yield and amino content were as indexes．The optimum conditions were the mol ratio of N．N-methylene bisacrylamide and diethylene triamine was 1：1．2．the temperature Was 80℃and reaction time was 24h．The significance test indicated that the reaction temperature had a significant effect on the yield and the content of amino groups． The infrared spectrum showed that NHE．HBP molecules were successfully synthesized according to expected route．ne determining result of NH2-HBP by using gel permeation chromatography showed that the number average molecular weight was up to 2088，and the weight average molecular weight Was up to 2472．111e synthesis of NH2-HBP was reproducible and stable．the average yield of NH2-HBP was 90．23％，the average amino content of NH2．HBP was 2．72mmol／g，as well as the production rate and variation coefficient of amino content we