导电聚合物纳米颗粒的制备及其沉降行为研究膜科学与技术专业论文.docxVIP

摘一要近年来，同时具备导电性和铁磁性的导电聚合物纳米复合材料的制备 摘一要 近年来，同时具备导电性和铁磁性的导电聚合物纳米复合材料的制备 引起了越来越多关注，成为研究的热点方向之一。导电聚合物与磁性纳米 粒子复合，可实现电、磁性能的复合，是开发同时具有电、磁性能的功能 材料的理想选择之一，是制备电磁屏蔽材料(膜)、电磁波吸收剂(膜) 等功能材料的重要途径。 使用原位聚合法成功的制备了PPy／Fe304磁性纳米颗粒复合物。首先 通过化学共沉淀法制备了Fe304磁性纳米颗粒，在此基础上通过原位聚合 法合成了导电聚合物／Fe304磁性纳米复合颗粒。制得的磁性纳米复合颗粒 粒径为100nm左右，Fe304磁性纳米颗粒的粒径为10 nm左右，且完全被 聚吡咯包覆。吡咯与Fe304的浓度比是影响形貌的重要因素之一。在浓度 比介于0．25—0．5之间时，聚吡咯／Fe304复合物的形貌均为颗粒状。但随着 吡咯浓度的增加，复合颗粒的粒径逐渐增大，粒径分布也变得更宽。氧化 剂加入顺序对磁性纳米颗粒复合物的形貌影响不大。· 应用纳米颗粒必须要解决其在介质中的分散性及稳定性问题。本研究 考查了电解质、高聚物、外加磁场对磁性纳米复合颗粒的沉降行为的影响， 同时研究了上述物系对其它形貌导电聚合物沉降行为的影响。 关键词： 导电聚合物聚吡咯磁性纳米粒子纳米复合材料膜材料沉 降吸光度 ABSTRACTThe ABSTRACT The small size of nanoparticles，which is responsible for the different properties of nanoparticles and nanostructured materials with respect to the bulk material such as electronic，optical，magnetic，chemical and mechanical et a1．，makes them suitable for new promising applications．Conducting polymer nanocomposites with both electrical and ferromagnetic properties have generated tremendous attraction，and they have become one of the most active research areas．Multi·component conducting polymer systems with nanoparticles of rectal oxides can be tailored to exhibit．besides novel electrical，magnetic and optical propertied，also good film forming and processing properties．These materials are largely being used in nonlinear optics，electrochemical display devices，molecular electronics，electrical and magnetic shields and microwave absorbing materials．The large surface to volume ratio of the nanoparticles results in the formation of composites with unusual physical and chemical properties，which are quite different from the composite due to interaction at the molecular level． A facile method to prepare conducting polymer／Fe304 magnetic nanoparticles was developed．Fe304 nanoparticles were prepared first by chemical CO-precipitation．Then polypyrrole(PPy)／Fe304 magnetic nanocomposite was prepared by in—situ polymerization in the presence of Fe304 nanoparticles．The mole ratio of PPy to