侧链“悬挂”偶氮苯小环的功能性聚合物的精密合成与其性能.pdfVIP

Abstract A Novel Polymer with Cyclic-Azobenzene Pendants ：Fine Synthesis and Investigation on Its Properties results indicated that the cyclic-azobenzene had higher Tm than its linear precursor linear-azobenzene. Besides, the glass transition temperature (T ) of Pcyclic-AzoMMA was g measured by differential scanning calorimetry (DSC). Compared with linear azobenzene side chains Plinear-AzoMMA possessed similar structure, Pcyclic-AzoMMA showed higher T than Plinear-AzoMMA. g (B) The UV-vis absorption changes of photo-induced trans-to-cis isomerization of the linear-azobenzene, cyclic-azobenzene and Pcyclic-AzoMMA in THF were investigated by irradiation with 365 nm UV light, and their thermally-driven cis-to-trans recovery were carried out through heating irradiated samples in the water-bath at 40 oC. Cyclic-azobenzene had higher trans-to-cis rates and slower cis-to-trans rates than its precursor. Besides, unlike the cyclic-azobenzene, the Pcyclic-AzoMMA shows much smaller cis-to-trans rates. (C) The fluorescent emission of linear-azobenzene and cyclic-azobenzene in THF solutions were investigated before and after irradiation with 365 nm UV light. The cyclic-azobenzene has stronger fluorescence emission than its linear precursor at room temperature. After the UV light irradiation, the fluorescence intensities of the cyclic- and linear-azobenzene solutions increased with the irradiation time. However, Pcyclic-AzoMMA in THF solution showed no fluorescence emission before or after irradiation with 365 nm UV light. (D) The SRG formation and optic