超细W(Mo)基复合粉末的制备与其性能分析.pdfVIP

5. 通过线扫描和点扫描的能谱分析研究了 W 与 γ-(Ni,Fe)之间的固溶 度与烧结温度的关系。结果表明，W 在γ -(Ni,Fe) 中的固溶度远大于γ-(Ni,Fe) 在 W 相的固溶度。在固相烧结范围内，随着温度的升高，W 在 γ-(Ni,Fe) 中的固溶度明显上升。当温度上升至 1500℃烧结温度下，W 从 γ -(Ni,Fe) 中析出，固溶度反而下降。 6. 所制备的W-Ni -Fe 粉末具有良好的烧结性能。当烧结温度为 1350℃ 时，其相对密度可达92% 。当烧结温度为 1450℃时，致密度达96% 以上。 烧结体中 W 晶粒约为 3μm ，其拉伸强度和抗弯强度最高可达 650MPa 和 1359MPa。抗弯强度和拉伸强度的上升曲线呈现出与致密化曲线不同的趋 势，主要是经 1500℃烧结所得烧结体因温度过高而导致W 颗粒严重长大， 力学性能显著下降，产生过烧行为。 7. W-Ni -Fe 烧结体的拉伸强度与烧结体的W 晶粒尺寸和拉伸的断裂机 制有关。固相烧结时，烧结体虽晶粒细小，但是颗粒之间粘结力小，拉伸 断面呈现为脆性断裂，拉伸强度较低。但是随着烧结体温度的增加，致密 度增大，断面中穿晶解理增多，当烧结温度为 1450℃时，拉伸断面以 W 晶粒内穿晶解理断裂和粘结相的撕裂为主，呈现韧性断裂。但是当烧结温 度为 1500℃时，W 晶粒急剧长大，呈延性断裂方式。 关键词：Mo-Cu 材料；W-Ni -Fe 材料；超细粉体；甘氨酸-硝酸盐法；烧结 性能；显微结构 2 Preparation and characterization of superfine W(Mo)-based composite powders Abstract Powder metallurgi cal W(Mo)-based alloys are widely used in electrical contacts, aerospace devices and many other components due to their high density, good electrical and thermal conductivity. They have attracted considerable attention in military and civilian. The development of modern science and technology puts forward higher requirements on W(Mo) -based alloys, and preparation of nanocomposite powder and fine -grain alloys have attracted much attentions. Fine-grain W(Mo)-base alloys with homogeneous microstructure have excellent comprehensive properties . Therefore, development of W(Mo)-based alloys has become one of the main topics in W(Mo)-based alloys. Nano sized powder s can improve ability, reduce sintering temperature and refine microstructure. It is desirable to prepar e superfine or nanosized W(Mo) based alloys. Furthermore, the sintering process a