改性al2o3作载体制备过渡金属磷化物催化剂工业催化专业论文.docxVIP

Preparation Preparation of Transition Metal Phosphide on Modified A1203 Abstract With the demand of the industrial development improving，more efficient and less cost catalyst in hydrofining field is eagerly needed．Because of the outstanding performance of the transition metal phosphide catalyst,its under a high expectation．As it has deep hydrogenation activity and great sul缸tolerance．it’S broadly studied in HDS and HDN field and applied in aerospace and material field．However，the preparation of transition metal phosphide catalyst，especially supported catalyst，is still a difficult problem．It has been a barrier for further development．Specifically，the problem include high cost on preparation and rigor conditions． The supported transition metal phosphide uses Si02 that has weak interaction force wim P in many literatures．Using A1203，which broadly applied on industry，as a carrier to support transition metal phosphide during the preoperational process，the production of A1P04 makes the process more difficult．So，modified—A1203 and using low valence phosphorus source can solve the difficult problem on the preparation． In this paper，we used solvothermal method，low-temperature combustion synthesis method and coprecipitation method to prepare A1203(syn)，Ce-A1203 and Ti．A1203 separately． And we mainly used(NH4)2HP04 as phosphorus source to prepare catalyst with equivalent—volume impregnation method．We used phosphorous acid that had lower valence state as phosphorus source for preparation of CoP．Thus，the preparation process Was simplified and the reduction temperature was fell off．Then，we used XRD，N2 absorption and NMR to represent modified—A1203 and catalyst． Finally，we used DBT as sulfocompound (reaction temperature was 280·360。C，reaction pressure was 4 MPa)to observe HDS performance on the catalyst． As for preparation，XRD pattern of catalyst and NMR of A1203 indicated that Ce-A1203 and A1203(syn)，the two kinds of modified-A1203，had a lot of A1”while it was only has a littl