水中邻苯二甲酸酯类化合物的预富集-环境科学.PDF

1998 1 EN V IRO N M ENT A L SCIEN CE Jan . , 199 8 * 金朝晖　黄国兰　李红亮　孙红文　陈勇生 ( , 30007 1) D4020 . , D4020 . pH . 116m m, 5m l/ min, pH 7. 0, 0. 5m l/ min , DBP DE HP 93. 6% 83. 0% , . , , , , . Enrichment of Phthal ate Esters in Water Jin Zh aohuiH uang Guolan L i Ho ng liang Sun Hong w en Chen Y ongsheng ( D epart ment of E nv ironment al Scien ce , N ankai U niv ersit y , T ianji n 30007 1) Abstract In t his st udy, D4020 macro -ret iculat e resin w as u sed f or t he f ir st time as an ab - sor bent for pht halat e est ers ( PEs) in w at er . T he result s show ed t hat D4 020 resin h as larg er ad - sor pt ive cap acit y, rap id adsorption rat e, tim e-saving , low co st and easy op er at ing. U sing a ho me- made adsorpt ion colum n , variou s f act ors w hich inf luence t he adsorpt io n and desorpt ion ef ficien - cies w ere investig at ed. T he r ecoveries ar e mainly dependent on column l engt h , f low rat e of t he eluant and p H v al ue and desorpt io n rat e. Recoveries ar e t he best w hen col um n leng t h, flo w rat e, p H value and desorption rat e are 116mm , 5m l/ min , 7. 0 , 0 . 5ml/ m in respect ively, but less aff ect ed by sal init y . R ecoveries of t he w ater sample are 93. 6% fo r D BP and 83 . 0% f or DEHP w ith good r eappearance. Keywordsphth alat e est er s, enrichment , adsor pt ion , deso rpt ion , U V phot o metry . , Ro hm Hass D4020 , 20 10- 9 , 50 , C18 ( 10m) , . , ( A . - R . ) , , 1621 , [ 13] ( A . R. ) , . , , , 232 1 , , ( A . R . ) [ 4, 5] ( . . ) , . , . A R D4020 752C ( , .