介质阻挡放电等离子体脱除氮氧化物的发射光谱研究-物理化学专业论文.docxVIP

介质阻拦放电等离于体8≈除暮氧汜餐的裳譬专音研究Optical 介质阻拦放电等离于体8≈除暮氧汜餐的裳譬专音研究 Optical emission diagnostic of NO removal in dielectric barrier discharge(DBD)plasma The o面cal emission spcclloscopy has been applied 10 study the emission spectra fiom N2， NO／N2，OdN2 and NO／O／N2 plasmas with dielectric barrier discharge(DBD)at atmospheric pressure．The experimental results are as follows： 1．ne emission spectra ofN，in DBD plasma has been measured．The lines attributed to 泓Cj n u-B’17a wele abtained．Excited niu-ogen atom was detected in 600～900 nm．The relationship between the intensity ofN2(C5nu-B3na and the gas flowrate WaS measureA．ne intensityofN2(C3neB3nodecreasedwiththeincreasingofthegasflowrate． 2．田1e emission spectra ofNO／N2．O们q2and NO／02／N2in DBD plasmas produced by ac power sourceⅥ，ith frequency of 50 Hz and 5 kHz respectively Was measured．The vibrational band ofNO(Az∑’-：掣玎)was detected．The concentrations oft．he gas m／xtures黼measured by using cll∞1inuorescenc∞Nq analyzer，N：O infrared absorbed gas aⅡalyzer and MS．It was discussed that Nrs)and N2(A)wel-e responsible for the nitrogen oxides conversion in nonthermal nitrogen plasma． 3．Choosing C‰C21-Land C2H2 which were often used to study the removal ofNOx in the presence of eXCeSS oxygen,We measured the emission spectra of C H假e C捌V№， No／G}“№，NO／G，H，。／o加b(C。}k=CH_e越，，C2H2)in DBD口la锄a-1k lines ofCH(A2 △-x2n)(0，o)，CN(B2∑+．X2∑+)(0，o)and C2(A3nrX3Ⅱ0(o，o)w雠detected．nle effect 011 the NOxremoval ofhydmcarbom in DBD plasma w鹋analyzed． Key Words：dielectric barrier discharge；emission spectra；NO；nitrogen atom； hydrocarbons ．Ⅱ一 独创性说明作者郑重声明：本硕士学位论文是我个人在导师指导下进行的研究 独创性说明 作者郑重声明：本硕士学位论文是我个人在导师指导下进行的研究 工作及取得研究成果。尽我所知，除了文中特别加以标注和致谢的地方 外，论文中不包含其他人已经发表或撰写的研究成果，也不包含为获得 大连理工大学或其他单位的学位或证书所使用过的材料。与我一同工作 的同志对本研究所做的贡献均己在论文中做了明确的说明并表示了谢 意。 作者签名： 童Jj岛 日期：邋《：丝 大连理工大学硕士学位论文1．1前言 大连理工大学硕士学位论文 1．1前言 物质的存在状态随着温度的上升一般会呈现出固态一液态一气态三种物态的转化过 程。对于气态物质，温度继续上升至几千度时，物质分子热运动加剧，相互间的碰撞会 使气体分子产生电离，这样物质就变成由自由运动并相互作用的正离子和电子组成的混 合物。我们把物质的这种存在状态称为物质的第四态，即等离子体。 等离子体中正电荷总数和负电荷总数在数值上总是相等的，