介质阻挡放电等离子体转化甲烷过程的动力学模拟-化学工程专业论文.docxVIP

天津大学硕j．学位论文 天津大学硕j．学位论文 摘要 摘 要 本文通过实验研究了常压下利用介质阻挡放电冷等离子体技术转化甲烷的 过程规律，考察了介质阻挡放电的特点及工艺参数对反应的影响。 通过机理分析，本文探讨了上述反应过程的动力学特点：选取17种粒子所 涉及的43个基元反应，建立了介质阻挡放电等离子体转化甲烷的反应网络，推 导出电子一分子(自由基)反应速率常数的计算公式，根据反应条件估算了介质 阻挡放电CH。等离子体中的平均电子能量，得到输入功率同放电中电子密度的 天系。 利用所建模型对甲烷转化产物随停留时间、输入功率及反应温度的变化情 况进行了计算机模拟，模拟计算结果可以较好地吻合实验数据，说明所建模型 ————————_，_一 是可靠的。 r —～、I通过实验与计算机模拟，本文还得到如F结论： ＼ l实验条件下介质阻挡放电等离子体甲烷转化C：烃的量依次为：C：H。) C2H2)C2H4； 2实验条件下介质阻挡放电CH。等离子体中的平均电子能量值范围为 8．2～8．8eV： 3实验条件下放电间隙中电子浓度数量级为1010cm一： 4高能电子同甲烷分子的碰撞解离反应是引发整个反应体系的关键。、：}／ ／ 关键词：介质阻挡放电，等离子体，甲烷，夥苏擎，雀藏 灭津大学硕士学位论文 灭津大学硕士学位论文 摘要 Abstract In this papeL the conversion of methane using dielectric—barrier discharge of cold plasma reaction at atnlosph谢c pressure、、+as carried out；the principals of dielectric。 barrier discharge and the effect of the discharge parameters on the methane conversion were discovered． By analyzing of the reaction mechanism，we discussed the dynamic rules of the conversion reaction：selected 43 radical reaction which 1 7 particle concemed and built the reaction nerork of methane con、rersion；deduced the calculation of reaction rate constant of electron—molecule(or radicals)reaction；estimated the average electron energy in dielectric—barrier discharge methane plasma；gained the relation between the input power and electron density． On the base ofthe model we had built，the relationships between consistencies of products in methane conversion and retention time，input power and temperature were simulated；the simulation result had a good coherence with the experiment data， which validated the validity ofthe model we had built． Due to our experiment and simulation，we also got the conclusion as follows： 1 Under the condition of dielectric—barrier discharge plasma,the order of C2 hydrocarbon product consistencies is C3H^)C2H2)C2H4； 2 The average electron energy in dielectric—barrier discharge methane plasma is 8，2-8．8 eV； 3 The quantity ofthe electron densit3，in the gap is 1 010cm-3； 4 The dissociation reactions between hi曲·en