减水剂对不同铝酸盐水泥水化凝结行为的影响-材料学专业论文.docx

万方数据 万方数据 摘要 FS10 对于四种铝酸盐水泥都起到延缓水化的作用，且加入量对 Secar71 和 CA270 水泥的水化时间影响很大。FCA70 水泥浆液的电导率测试表明 FS10 使水 泥水化的诱导成核期延长，但 FS10 却促进了水泥砂浆的凝结。 对处在水化过程中的水泥在特定时间进行冷冻真空干燥的方法可以很好地 用来分析水泥水化过程中的物相和显微结构变化。对水化放热峰前后的物相分 析，印证了 STP 的促凝和 CA 的缓凝作用以及温度对水泥水化的影响。 关键词： 铝酸盐水泥 水化 三聚磷酸钠 柠檬酸 FS10 II Abst Abstract Abstract There are many factors which could have influence on the hydration of calcium aluminate cement in the refractory castable system. The characters of the cement and the additives in the castable system are the two important factors. However, there are few literatures which compare the hydration behavior of the same-grade commercial cements from different companies, or study the changes of hydration behavior of these cements when some dispersants are added. In this paper, four CA-70 type commercial calcium aluminate cements from home and abroad were chosen as the research object, which are CA70, Secar71, CA270 and FCA70. Heat evolution, electrical conductivity and setting time of the cement paste or mortar at different curing temperatures were tested, freeze vacuum drying method was utilized to terminate the cement hydration at the designated times and X-ray Diffraction and SEM were conducted to analyze the phases of the hydrated products. The hydration and setting behavior differences of the four cements with and without dispersant (STP, CA and FS10) were analyzed. The results illustrate that CaO and Al2O3 are the two major chemical components of the four CACs, whose total content accounts for more than 98%. The main phases of the CACs are CA, CA2 and ?-Al2O3, but their contents are different in each of the cements. Cement CA70 has less CA phase; CA2 content is lower in CA270 and FCA70; Cement CA270 and FCA70 both have a lot of ?-Al2O3. The sequence of the cements by specific surface area is FCA70CA70Secar71CA270. Comparatively, the hydration of CA70 and FCA70 is fast at curing temperature from 10?C to 40?C, while the curing temperature has a marked impact on the hydration of Secar7