水性聚氨酯的交联改性及其性能-高校化学工程学报.PDF

第23 卷第4 期 高 校 化 学 工 程 学 报 No.4 Vol.23 2009 年 8 月 Journal of Chemical Engineering of Chinese Universities Aug. 2009 文章编号：1003-9015(2009)04-0650-05 水性聚氨酯的交联改性及其性能 罗春晖, 瞿金清, 陈焕钦 ( 华南理工大学 化学与化工学院, 广东 广州 510640 ) 摘 要：阴离子水性聚氨酯(PU)含有羧基起内乳化剂作用稳定水性聚氨酯分散体(PUD)，同时也使PU膜具有高的亲水 性。为提高PUD涂膜性能，采用氮丙啶和聚碳化二亚胺对其进行交联改性。利用红外光谱和热重分析表征了PUD 固化 涂膜，结果表明：在室温下氮丙啶和聚碳化二亚胺可与PUD链上的羧基反应，PUD涂膜性能的提高取决于固化剂种类： 如氮丙啶能显著改善涂膜耐水性、耐溶剂性及耐污染性，因其能提高涂膜的凝胶含量至92.63% ，涂膜硬度至0.72 ，其 最佳的氮丙啶与羧基的质量比为5.84 ；另一方面，聚碳化二亚胺能改善涂膜的附着力、柔韧性及抗冷脆性，最佳的聚 碳化二亚胺与羧基的质量比为10.37。TGA 曲线表明聚碳化二亚胺能提高PUD涂膜的热稳定性，而氮丙啶则降低涂膜的 热稳定性。 关键词：水性聚氨酯；交联改性；氮丙啶；聚碳化二亚胺 中图分类号：TQ630.4 文献标识码： A Crosslinking Modification of Aqueous Polyurethane Dispersions and its Properties LUO Chun-hui, QU Jin-qing, CHEN Huan-qin (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China ) Abstract: Anionic aqueous polyurethane (PU) contains the carboxyl groups which serve as internal emulsifier stabilizing aqueous PU dispersions (PUD); at the same time, it causes the PUD film to exhibit a high hydrophilicity. In order to improve the performances of PUD film, the PUDs were crosslinked by aziridine derivatives and polycarbodiimide, respectively. The crosslinked PUD films were characterized by FT-IR spectrum and thermogravimetric analysis (TGA); the results indicate that the aziridine derivatives and polycarbodiimide react with the carboxyl groups of PUD at room temperature. The properties of the cured PUD film were improved according as