键合型铕配合物发光薄膜的制备及性能研究-物理化学专业论文.docxVIP

中山大学硕士毕业论文Preparation，properties 中山大学硕士毕业论文 Preparation，properties of bonding—type europium complex thin film Major：Physic chemistry Name：Haolang Hu Supervisor：Yangyi Yang ABSTIRACT A europium complex，with high luminescence and polymeric groups，was synthesized by mixing 1，10-Phenanthroline(phen)，acrylic acid and europium chlorides．The complex was characterized by elemental analysis and FTIR，which indicates that the complex is Eu(AA)3Phen，and the central ions are coordinated by acrylic acid with carboxyl oxygen atoms and phen with nitrogen atoms．Fluorescence spectra show that the complex emitting intense fluorescence and has good color purity． The bonding-type rare earth complex—organic polymer was prepared through the copolymerization ofthe monomers ofmethyl methacrylate、acrylic acid and europium complex with C=C bonding structure，and the thin film Was achieved by put the viscous prepolymerization solution along the quartz slides．The structural and the luminescence properties for this polymeric composite material were studied with FTIR，TGA，fluorescent excitation and emission spectra．The FTIR spectrum of P(MMA-CO·AAl Was changed after added the europium complex，suggesting there are some interaction between the guest and the host，The hybrid thin film shows the strong red characteristic emission of europium(III)ions and the relative intensity is stronger than that of europium complex monomer,which indicates the P(MMA-CO—AA、copolymer is a suitable substrate for the luminescence of europium complexes． Keywords： Europium complex；Coordination polymer；Luminescence thin film； Rare earth-organic hybrid material 中山大学硕士毕业论文第1章绪论 中山大学硕士毕业论文 第1章绪论 1．1引言 稀土金属和有机高分子的复合材料既具有稀土离子独特的光、 电、磁等特性，又具有高分子材料质量轻、抗冲击力强和易加工成型 的优良性能，是极具有潜在应用价值的功能材料。在稀土功能材料的 发展中，尤其以稀土发光材料格外引人注目。我国拥有发展稀土应用 的得天独厚的资源优势，在现已查明的世界稀土资源中，80％的稀土 资源在我国，并且品种齐全。但应该清醒的看到，我国在稀土深加工 方面，在稀土功能材料的开发和应用技术方面并不站在世界前列，与 世界先进水平还有相当大差距，需要我们奋起赶上。[1l 稀土高分子材料泛指稀土金属离子以掺杂或键合的方式复合于 高分子基质中的聚合物。20世纪60年代初，由于小分子稀土配合物 特殊的荧光和激光性质，掀起了稀土配合物的研究热潮。在稀土配