节能型铜锰系高温变换催化剂的研究-工业催化专业论文.docxVIP

天津大学硕士论文 天津大学硕士论文 摘要 摘要 本文采用沉淀法制备了铜锰系列高温变换反应催化剂。利用微反装置评价了 铜锰系催化剂的催化活性、选择性和热稳定性：考察了催化剂中Cu／Mn比、单 一载体、铝基复合氧化物载体对铜锰催化性能的影响。并以镁铝复合载体负载的 铜锰催化剂为重点，详细考察了催化剂中镁铝含量、制备条件、还原评价条件对 催化性能的影响。应用了差热分析法(DTA)、热重分析法(1’G)、x射线衍射 法(XRD)、程序升温还原(TPR)、红外分析(瓜)五种表征技术对铜锰系列催 化剂的物相结构、以及活性组分的分散状态、还原性能等进行了表征工作。并探 讨了铜锰系列催化剂的催化作用。 f研究结果表明，镁铝复合载体负载的铜锰催化剂可明显提高催化剂的活性， 尤其是低温活性，并可改善催化剂的热稳定性；在250℃-500℃内，没有发现任 何烃类副产物产生；并且对水碳比和空速变化有较好的适应能力，在低水碳比下 使用仍能保持高活性。 研究结果还表明，铜是主要的活性组分，锰有很好的辅助作用。CuMn20。 相是铜锰催化剂活性相的前驱态。催化剂活性组分存在两种价态的转换，有利于 形成电子循环，很可能是铜锰催化剂高活性的来源。镁铝复合载体表现出很好的 助催化性能，除与它们自身的特性有关外，还和它有利于CuMn20。相的形成、 稳定、分散，增强催化剂的吸水性，还原活化性能等密切相关。卜—r～ 关键词；变换反应铜锰系列催化剂镁铝复合载体活性评价 天津人学硕ij论文 天津人学硕ij论文 捅要 ABSTRACT In this paper,the Cu—Mn based hi【gh temperature water-gas shift reaction catalysts were prepared by precipitation method．The catalytic activity,selectivity and thermal stability of the catalysts have been evaluated by the laboratory tube reactor． The effects of Cu／Mn ratio，single supports，alumina based composed supports on the catalytic properties have been studied．Focused on the MgO—A1203 composed supports， the effects of the contents of MgO and A1203，preparation conditions，the reductive and reaction conditions on catalytic properties have been investigated．The phase structure，the dispersal state and the reduction property of catalysts have been investigated by the techniques of DTA，TG，XRD，TPR，IR，at the sam．e time the catalytic properties of Cu-Mn based catalysts are discussed in detail． The results show that the Cu-Mn catalysts，which supported On MgO-A1203 composed support，carl increase catalytic activity obviously,especially the low temperature activity,and improve the catalytic thermal stability．Further more，In the range of 250C-500C，no hydrocarbon byproducts+gala be detected．The Cu-Mn catalysts supported on MgO-A1203 composed support can adapt to the variation of H20／CO ratio an