姜黄素工业废水物化方法处理分析-环境工程专业论文.docxVIP

摘 摘 要 姜黄素工业废水产生于姜黄素生产的前期蒸馏、水解(在酸性或碱性条件下) 的混合废液及洗涤废水。本论文通过对姜黄素工业企业生产工艺调查及姜黄素工 业废水进行水质分析，确定姜黄素工业废水的水质特点及处理难点：姜黄素工业 废水属于高浓度有机废水，废水具有很低的酸度，废水的成份复杂，含有大量具 有较强的着色能力的难降解表面活性物质姜黄素衍生物，废水呈深茶色，废水的 可生化性差。 本论文研究发现在较低pH、温度时，YJD与PAM组合对姜黄素工业废水 具有较好的脱色絮凝沉淀效果；在较高pH值、温度时，絮凝剂A12(S04)3与助凝 剂PAM的组合具有较好的脱色絮凝沉淀效果。姜黄素工业废水经Fenton试剂氧 化、Ca(OH)2中和及PAM絮凝沉淀处理，废水有很好的脱色及COD去除效果。 通过试验研究发现溶液的反应起始温度、pH值、Fe2+的投加量显著影响Fenton 试剂氧化反应反应速度，并建立了温度、pH值、Fe2+三者与反应时间关系模型。 本研究选用了具有较大比表面积且大孔比例较高粒状活性炭进行姜黄素工业废 水吸附试验，试验发现在一定温度、pH值下，其对姜黄素工业废水有较好的脱 色、COD去除效果。在一定温度、pH值下，臭氧氧化对姜黄素工业废水具有较 好的脱色效果，对COD的去除也有一定的效果。试验发现活性炭吸附及臭氧氧 化协同作用对姜黄素工业废水处理效果明显优于单独使用活性炭吸附、臭氧氧化 的处理效果。根据试验研究结论及生产企业的特点推荐三套废水处理方案，并分 别对各方案作经济效益分析。 关键词： 姜黄素工业废水 脱色 Fenton试剂 臭氧氧化 活性炭吸附与臭氧氧化协同作用 ABSTRACTTumaeric ABSTRACT Tumaeric industry wastewater comes from the process of producing turmeric element， which is composed of waste mixture liquid of distillation and hydrolyzing(under acid or basic condition)and washing wastewater．Through investigating technics of turmeric factories and analyzing water quality of Turmeric industry wastewater,the thesis finds that Turmeric industry wastewater is belong to high density organic wastewater,that it is thick brown，that it has low acidity,that its component is complex，that it contains much turmeric ramification，which is dyeable and difficult degradable surfactant，and that its biodegradability is not good． The thesis find that the combined coagulating agent of YJD and PAM is very good at color removal，coagulation and sedimentation for Turmeric industry wastewater at low pH and temperature，while combined coagulating agent of A12(S04h and PAM is very good at high pH and temperature．Turmeric industry wastewater carl remove color and degrade COD well by Fenton’S reagent oxidation with Ca(OH)2 neutralization，PAM coagulation and sedimentation process．The experiment finds that start temperature and pH ofsolution and quality ofFez+added into effect the speed of Fenton’S reagent oxidation greatly．The thesis establishes the model of the ti