金属离子对煤焦-NO反应影响的实验研究-热能工程专业论文.docxVIP

华中 科技 大 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Coal is the chief energy in China. The combustion of coal discharge large quantities of pollutants, in which the NOx is serious harm to environment and human’s health. Many governments begin to control the NOX emissions by legislation. The coal-fired electric power plant is the main fixed source of NOx. The reburning , because of its significant advantages, becomes a choice among many technologies to reduce NOx emissions of power plant. The heterogeneous reaction between char and NO, which has an important position in the reaction mechanism of using pulverized coal to reburn, is quite a degree of concern. In this paper, a kind of bituminous coal and lignite were selected, respectively. The deashed coals were obtained by demineralized with acid washing. The chars were prepared by devolatilizing the deashed coals and their original coals in a horizontal quartz reactor at 1000℃. Pore size distribution and micro-morphology of the samples were investigated and analyzed. The result showed that the original char and deashed char from lignite had more micro-morphology than that from bituminous. NO reduction by coal and chars were investigated in a small quartz fluidized bed reactor. It was found that the heterogeneous reaction between char and NO was the main reaction in the NO reduction by coal. The influence of temperature, mineral matter in the coal and micro-morphology to the char-NO reaction was studied. The results showed that the reduction of NO was increased with temperature for all chars. The mineral matter in the different coals had different influence to the reaction. When the chars’ micro-morphology increased, the percent of NO reduction increased in step. The catalytic activities of sodium, calcium and iron on the reaction between char and NO were studied by adding metal ion to the deashed char. The results showed that Fe had the most catalytic activity. Adding 1% Fe was found to have the best effect when studied t