金(I)膦-硫混合配体配合物的合成与催化光降解芳基污染物性能研究-化学专业论文.docxVIP

II II 中文摘要 金(I)/膦-硫混合配体配合物的合成与催化光降解芳基污染物性能研究 关键词：金配合物；膦-硫混合配体；光降解；光催化；芳基污染物 作 者：亓海啸 指导教师：任志刚 教授 PAGE PAGE IV 金(I)/膦-硫混合配体配合物的合成与催化光降解芳基污染物性能研究 英文摘要 Two gold(I) complexes derived from P-S hybrid ligands: synthesis and catalytic performance in the photodegradation of aromatic pollutants Abstract In recent years, Au-containing materials have received much attention for their photocatalysis applications in organic reactions, hydrogen production by water splitting and the conversion of environmental pollutants. In the case of the conversion of pollutants, the known photocatalysts are usually Au nono-materials, but rarely Au coordination compounds up to now. In this thesis, a P-S hybrid ligand N,N-bis(diphenylphosphanylmethyl)-amino-thiocarbamide (dppatc) was selected to react with HAuCl4?4H2O. Two new complexes were separated and structurally determined. Their catalytic activities toward the photodegradation of nitroaromatics and azo pollutants in aqueous solutions were also investigated. The main contents of this thesis are described as follows: A minireview has made on the applications of Au-containing materials as photocatalysts in organic reactions, hydrogen production by water splitting and the conversion of environmental pollutants. Au coordination compounds are used as photocatalysts in organic coupling reactions, while Au nanoparticles and Au nanocomposites have been widely used as photocatalysts in the organic oxidation reactions, hydrogen generation by water splitting and the conversion of environmental pollutants. This indicates that Au-containing materials have good absorption toward light and can be used as photocatalysts. Solvothermal reactions of HAuCl4?4H2O with dppatc at 80 °C and 115 °C produced two Au-P-S complexes, [Au2(dppatc)2]Cl2 (1) and [Au2(dppmt)2]n (2) (dppmtH = (diphenylphosphino)methanethiol), respectively. 1 and 2 were characterized by elemental analyses, IR and UV-vis spectra, 1H NMR，31P NMR，thermal-gravity analyses, powder X-ray diffrac