钾盐添加量及煤焦粒度对两段组合式气化工艺的影响-中国电机工程学报.PDF

第 32 卷 第 5 期 中 国 电 机 工 程 学 报 Vol.32 No.5 Feb.15, 2012 2012 年 2 月 15 日 Proceedings of the CSEE ©2012 Chin.Soc.for Elec.Eng. 27 0258-8013 (2012) 05-0027-06 TQ 546 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 钾盐添加量及煤焦粒度 对两段组合式气化工艺的影响 苏攀，王亦飞，金渭龙，于广锁，王辅臣 (煤气化教育部重点实验室(华东理工大学) ，上海市 徐汇区 200237) Effects of Potassium Carbonate Loadings and Coke Particle Sizes on Combined Two Stage Coal Gasification Technology SU Pan, WANG Yifei, JIN Weilong, YU Guangsuo, WANG Fuchen (Key Laboratory of Coal Gasification of Ministry of Education (East China University of Science and Technology), Xuhui District, Shanghai 200237, China) ABSTRACT: Sensible heat of high temperature syngas could 在反应 30 min 时达到峰值，床层平均温降最高，达到 be used effectively by high-efficiency two stage combined coal 402.4 ℃。文中还研究了钾盐添加量对二段煤焦气化反应性 gasification technology, so as to enhance the cold gas 能的影响，钾的添加量应大于 5%才能明显体现其良好催化 efficiency in the current entrained-flow gasifier. Gasification 效果。碳酸钾用量在 8%下的催化效果显著，二段出口有效 reactivity of coke was investigated under different ranges of 气体浓度和碳转化率等参数提高明显，二氧化碳累积转化率 size distributions in the secondary bed. The experiment results 为 19%。此工艺有效实现 CO2 减排和资源化利用，环境效 show that the optimal size range is 10~15 mm size. Under this 益良好。 size distribution, carbon dioxide cumulative conversion is 10%. 关键词：两段式气化工艺；有效气浓度；碳转化率；碳酸钾 reaction rate reaches the peak value after 30 min’ reaction, and the average temperature drop of the secondary bed was t