毕业论文-城市内河沉积物中硫化物(AVS)测定.docVIP

城市内河沉积物中硫化物含量测定 PAGE 2 本科毕业设计 环境工程 城市内河沉积物中硫化物(AVS)测定 Measuring acid volatile sulfide in urban river sediments PAGE II 城市内河沉积物中硫化物（AVS）测定 【摘要】为了解决城市内河沉积物中酸性可挥发硫化物（AVS）的常规测定，对经典的碘量法、离子选择电极法、冷扩散法进行改进，建立了吹气吸收法、改进的冷扩散法、内循环吹气吸收法、内循环冷扩散法四套简易的仪器装置和分析程序。实验表明：内循环吹气吸收法具有装置简单、操作简便、反应时间短、准确度高、可同时测定多组样品的优点，更加适合城市内河沉积物中AVS的常规测定，而内循环冷扩散法作为进一步研究的方向。用改进的冷扩散法测定了采自宁波市城市内河的沉积物样品，得到了内河中AVS的含量。 【关键词】内河沉积物；酸性可挥发硫化物（AVS）；测定方法。 Measuring acid volatile sulfide in urban river sediments 【ABSTRACT】For the routine measurement of acid volatile sulfide (AVS) in urban river sediments, the earlier published iodimetry method, the diffusion method and the ion selective electrode method were adapted and improved, four kinds of simple devices and analytical procedures: the purge-and-trap method, the adapted diffusion method, the inner loop of purge-and-trap method, the inner loop of diffusion method, were established. Through future measurement and analysis, We conclude that the inner loop of purge-and-trap method has the advantage of the device simple, easy to operate, short reaction time, simultaneous determination of multiple samples, therefore, it is more suitable the routine measurement of acid volatile sulfide (AVS) in urban river sediments. And it pointed out that taking the inner loop of diffusion method as the direction for further research. Through analyzing the sediment samples from Ningbo urban river analyzed with the adapted diffusion method, obtaining the content of AVS in part of urban river. 【KEYWORDS】river sediments；acid volatile sulfide(AVS)；measuring method。 目　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc292720994 1 前言 PAGEREF _Toc292720994 \h 3 HYPERLINK \l _Toc292720995 1.1 城市内河沉积物中硫化物的种类 PAGEREF _Toc292720995 \h 3 HYPERLINK \l _Toc292720996 1.2 城市内河沉积物中硫化物的形成 PAGEREF _Toc292720996 \h 3 HYPERLINK \l _Toc292720997 2 国内外研究现状与意义 PAGEREF _Toc292720997 \h 4 HYPERLINK \l _Toc292720998 2.1 城市内河沉积物中硫化物的分布特征 PAGEREF _Toc292720998 \h 4 HYPERLINK \l _Toc292720999 2.1.1 沉积物中硫化物的季节波动 P