炉衬产生的氧对真空钢液脱氮的动力学影响.PDF

第 24 卷第 4 期 　　　 特殊钢 　 Vol. 24. No. 4 　　　　 2003 年 7 月 　　　　　　　 SPECIAL STEEL 　 July 　2003 　　　　 ·13 · 炉衬产生的氧对真空钢液脱氮的动力学影响 孙铭山 　丁伟中 　鲁雄刚 (上海大学钢铁冶金重点实验室 ,上海 200072) 摘　要 　采用 99. 99 %氧化镁砂捣打炉衬的 20 kg 真空感应炉 ,研究了超低碳钢熔炼时炉衬产生的氧对 真空钢液脱氮的影响。试验结果表明 :钢液中氧含量在 120 ×10- 6 时 ,脱氮的限制性环节是界面化学反应 ; 随 炉衬中氧的逸出 ,当钢液中氧含量在 510 ×10- 6 时 ,真空钢液脱氮处于界面化学反应和液相边界层扩散控制的 边缘区域 ,脱氮速率降低。 关键词 　炉衬 　氧含量 　真空 　钢液脱氮 　动力学 Kinetics Influence of Oxygen Releasing from Furnace Lining on Removal of Nitrogen in Steel during Vacuum Smelting Sun Mingshan , Ding Weizhong and Lu Xionggang ( ) Shanghai Enhanced Laboratory of Ferrometallurgy , Shanghai University , Shanghai 200072 Abstract 　The influence of oxygen releasing from furnace lining on removal of nitrogen in extralow carbon steel dur ing smelting has been studied using 20 kg vacuuminduction furnace with 99. 99 % magnesia rammig lining. The test results - 6 show that as the oxygen content in molten steel being 120 ×10 , the removal of nitrogen is limited by interface chemical - 6 reaction , and while the oxygen content in molten steel being 510 ×10 , the removal of nitrogen is in border zone controlled by both interface chemical reaction and liquid borderline diffusion led to the decrease in removal rate of nitrogen. Material Index 　Furnace Lining , Oxygen Content