海底混输管道水合物生成对析蜡的影响研究-油气储运工程专业论文.docxVIP

摘 摘 要 对于较低环境温度下运行的海底油气水混输管道，蜡和水合物可能同时生成。这将 造成管道的严重堵塞，引发严重的安全问题并带来巨大的经济损失，故研究海管混输状 态下蜡和水合物的生成显的尤为重要。以往学者大多单独研究蜡或水合物的形成，没有 考虑二者之间的相互影响。实际上，水合物或蜡的形成会改变流体的组成，影响另一方 的热力学行为。 为研究蜡与水合物之间的关系，本文从热力学角度对水合物存在的体系析蜡情况进 行了研究。分析了相平衡理论以及模型的数值算法。在前人提出的蜡模型的基础上进行 了优选，并编制了预测相平衡的程序。利用此程序对大量的体系进行了蜡相平衡的模拟， 并与实验结果进行了对比。结果表明，模型能较好的进行蜡相平衡的预测。对于水合物， 本文采用模拟软件中水合物模块对其进行相平衡模拟计算。 对于同一体系，单独进行水合物生成以及析蜡情况的模拟计算。对于水合物先生成 的情况，进行水合物的闪蒸计算以此更新水合物生成后流体的组成，然后重新进行析蜡 计算。对比无水合物情况及水合物存在情况体系析蜡温度的变化情况，得出水合物的生 成对析蜡的影响主要取决于水合物的生成引起轻组分含量变化的多少，轻组分含量变化 越大，其对析蜡的影响越大，反之亦然。对于本文研究的体系，水合物的生成对析蜡的 影响不是很大。 关键词：析蜡，水合物，热力学相平衡 The The Study on The Influence of Hydrate on Wax Appearance in Subsea Multiphase Pipeline Wang wei(OilGas Storage and Transportation Engineering) Directed by Prolessor Kou Jie A bstract Wax and hydrate could occur in the subsea multi-phase pipelines，which works at the lower environmental temperature．It can block the pipelines and lead to serious security problems and huge economic losses．So it is particularly important for US to investigate the formation of wax and hydrate in subsea multi·phase pipeline．However，these two solid depositions were mostly studied independently in previous work without considering the interaction between them．Actually,the formation of hydrate or wax will change the composition of the fluid，which could affect thermodynamics behavior of the other． To study the relationship of them，this paper did the work on the precipitation of wax with the existence of hydrate in thermodynamics ways．Phase equilibrium theory and numerical algorithm of the model were discussed．We did selection and optimization on the basis of previous Wax models．A procedure was present for simulate phase equilibrium of wax． It was tested for a large number systems comparing with the experimental results，which lead to a good representation．We adopted hydrates module of simulation software to simulate hydrates phase balance calculation． The simulmions were carried on for the formation of hydrate and the appearance o