含吡唑配体的过渡金属配合物的结构和性质研究-无机化学专业论文.docxVIP

南开大学硕士学位论文Abstract 南开大学硕士学位论文 Abstract Molecular magnetism of polynuclear complexes and supermolecular self-assembly of coordination polymers are currently focuses in the field of coordination chemistry．In this thesis，fifteen new polynuclear complexes with tpm (tris(pyrazoly)methane)，bpm(bis(pyrazoly)methane)and bpm8(his(3， 5-dimethyl·pyrazoly)methane)as terminal ligands and phthalate，dca(dicyanamide) and SCN‘as bridged ligands have been synthesized and determined by X—ray crystallographic methods，six of which are coordination polymers with infinite structures．Furthermore，they have been characterized by means ofelemental analysis， IR，electronic spectra，ESR,cyclic voltammograms and varible—temperature magnetic suseeptibility measurements． 1- Six unique 3d-metal coordination polymers showing infinite chain have been synthesized．Three of them are bridged by phthalate，two of them linked through dca and one of them with sulfate ion as the bridged ligand．The varible-temperature magnetic susceptibilities of 1 D copper complexes with isophthalate as bridged ligand exhibit that the exchange interaction between copper(II)ions was ferromagnetic． 2． Four new zero-dimensional coordination complexes by using pyrazole and its derivate have been synthesized including one mononuclear and three dinuclear species． 3．Two half-sandwich complexes using SCN’as bridged ligand have been synthesized．The new self-regulating ligand K[H2B(tz*)2] (tz+： 3,5-dimethyl-1，2，4-triazolyl)and its copper and zinc complexes have been synthesized．The weak interaction among the complexes has been studied． Keywods：pyrazol岛one—dimensional polymer,polynuclear complexes,crystal structures,magnet如m，spectroscopic properties． -111． 壹墅奎兰堡主堂垡笙茎 壹墅奎兰堡主堂垡笙茎 一 一一一 晶体表 本论文中讨论共15个单晶已经被收录到剑桥晶体数据库，下表中列出了论 文各章节中记录的单晶的分子式，剑桥晶体号和性质测定。 No． Formula Summary of Data Properties 3．1 C19H25ClCu3N1206 CCDC 196154 IR，UV 3．2 C26H40Cu2N16010S2 CCDC 197376 IR／Lrv／CV 3．3 C24H36Cu2N16吼oS2 CCDC 196152 IR几Jv 4．1 C)7H40Cu2N12013 CCDC 196145