毕业论文-铁酞菁负载纤维素纤维处理有机废水.docVIP

PAGE 本科毕业论文 （20 届） 铁酞菁负载纤维素纤维处理有机废水 专业：高分子材料与工程 摘要：本实验采用固相合成法得到四氨基金属铁酞菁，然后把四氨基金属铁酞菁以共价键的形式负载到纤维素纤维上，最后以负载了金属铁酞菁的纤维来催化氧化有机染料废水。并研究了反应温度，溶液pH和H2O2浓度因素对负载型金属酞菁处理染料废水的影响，当反应温度升高时，其催化效率有所提升；当pH为2时，H2O2浓度为6×10-3mol/L是其催化效率最宜的条件。 关键词：铁酞菁；负载纤维；有机废水 Iron Phthalocyanine Immobilized onto Cellulose Fiber for the Treatment of Organic Wastewater Abstract：In this paper, tetraaminophthalocyanine iron was synthesized through solid-phase method, the obtained tetraaminophthalocyanine iron was covlently immobilized onto cellulose fiber. The tetraaminophthalocyanine iron functionalized cellulose fiber was used for the treatment of organic dye wastewater. The influence of reaction temperature, pH value and H2O2 concentration on the catalytic oxidation behavior was discussed.The results show that it’s the catalytic efficiency increases with increase of reaction temperature. When pH is 2, the concentration of H2O2 is 6 x 10-3mol/L, the tetraaminophthalocyanine iron functionalized cellulose fiber has the highest catalytic efficiency. Key words： Iron phthalocyanine; Immobilized cellulose fiber; organic wastewater 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc292637358 1 引言 PAGEREF _Toc292637358 \h 1 HYPERLINK \l _Toc292637359 1.1研究背景 PAGEREF _Toc292637359 \h 1 HYPERLINK \l _Toc292637360 1.2研究现状 PAGEREF _Toc292637360 \h 1 HYPERLINK \l _Toc292637361 1.3研究目标与主要内容 PAGEREF _Toc292637361 \h 3 HYPERLINK \l _Toc292637362 2 实验部分 PAGEREF _Toc292637362 \h 3 HYPERLINK \l _Toc292637363 2.1实验原料与试剂 PAGEREF _Toc292637363 \h 3 HYPERLINK \l _Toc292637364 2.1.1 实验原料 PAGEREF _Toc292637364 \h 3 HYPERLINK \l _Toc292637365 2.1.2 实验仪器 PAGEREF _Toc292637365 \h 4 HYPERLINK \l _Toc292637366 2.2实验步骤 PAGEREF _Toc292637366 \h 4 HYPERLINK \l _Toc292637367 2.2.1四硝基铁酞菁的合成 PAGEREF _Toc292637367 \h 4 HYPERLINK \l _Toc292637368 2.2.2四氨基铁酞菁的合成 PAGEREF _Toc292637368 \h 5 HYPERLINK \l _Toc292637369 2.2.3四氨基铁酞菁负载于纤维素纤维膜的制备 PAGEREF _Toc292637369 \h 5 HYPERLINK \l _Toc292637370 2.2.4染料废水脱色效果的测定 PAGEREF _