毕业论文-亲水型涤纶织物柔软剂的制备与性能.docVIP

PAGE 本科毕业论文 （20 届） 亲水型涤纶织物柔软剂的制备与性能 专业：高分子材料与工程 摘 要：本文采用二步缩聚法，以对苯二甲酸二甲酯(DMT)、乙二醇(EG)、聚乙二醇4000（PEG-4000）和聚乙二醇2000（PEG-2000）合成了亲水型的具有柔软功能的聚醚酯。通过该聚醚酯与硅油类柔软剂的复配制备了亲水型的涤纶织物柔软剂。分别考察了该聚醚酯与氨基硅油以及亲水硅油（SRS）的复配比例对亲水性和手感（柔软性、平滑性）的影响。同时也考察了后整理条件（柔软剂浓度、烘焙温度）对该复配柔软剂手感的影响。试验结果表明：聚醚酯/氨基硅油=93/7时，保持一定的亲水性，手感较好；聚醚酯/亲水氨基硅油（SRS）在80/20-50/50（质量比）范围内进行复配时，亲水性能保持较好，柔软性和平滑性达到良好的水平。适宜的后整理（浸渍法）条件：柔软剂浓度为0.2%（o.w.f=2%）、烘焙温度为160℃。 关键词：聚醚酯；氨基硅油；亲水硅油；亲水性；柔软性；涤纶织物 The Preparation and Performance of Hydrophilic Type Polyester Fabric Softener Abstract：Poly(ether ester) were prepared using dimethyl terephthalate (DMT), ethylene glycol (EG) and polyethylene glycol (PEG) via sequential polycondensation, which is of hydrophilicity and softening function. A new hydrophilic type softener were prepared by mixing poly(ether ester) and silicon type softener. The effect of the formulating ratio of poly(ether ester)/aminosilicon and poly(ether ester)/ hydrophilic silicon(SRS) on hydrophilic and handle was investigated. The effects of finishing conditions such as concentration, drying temperature on softening performance of this formulating softener were also discussed. The experiment results showed that the formulating softener with a ratio of 93/7(m/m, poly(ether ester)/aminosilicon) providing certain hydrophilicity and soft hand to polyester fabric. The Poly(ether ester)/ hydrophilic silicon(SRS) formulating softener exhibited better hydrophilicity and softening performance (including softness and smoothness) within a range of 80/20-50/50. The optimal finishing condition is as follows: concentration of finishing agent is 0.2%（o.w.f=2%）and drying temperature is 160℃. Key words：poly(ether ester); aminosilicone; hydrophilic silicon; hydrophilic; softness; polyester fabric PAGE 5 目 录 1.引言………………………………………………………………………………1 2.实验部分……………………………………………………………………………2 2.1 实验原料………………………………………………………………………2 2.2 聚醚酯合成装置………………………………………………………………2 2.3 聚醚酯合成原理…………………………………………………………… 3 2.4 聚醚酯合成工艺………………………………………………