瓜尔胶衍生物的合成-应用化学专业论文.docxVIP

瓜尔胶衍生物的合成The 瓜尔胶衍生物的合成 The synthesis of guar gum derivatives Abstract Guar gum．a water-soluble natural polymer，is composed mostly ofploygalactomamaans which is essentially a straight chain mannan with single membered galactose branches’lhe mannose units are linked in a 1-4一．beta．一glycosidic linkage and the galactose branching lakes place by means of a 1—6 linkage on altemate mannose units．3he ratio of galactose to mannose in the guar polymer is，therefore，one to two．Guar gum is often chemically modified to improve its physical and chemical properties，SO that it can be used as thickeners for foods，paints．oil well fluids．pmxonal care products，and many other functional applications． t[ydroxypropy guar gum(HPG)is prepared by the reaction of guar gum with propylene oxide．NMR and IR are used to characterize the structure of HPG；spectrometry is also used to determine molar substitution．The synthetic procedure vca8 studied aS the base of the content of insoluble residue and the viscosity，them the best technical conditions were determined． Comparing with original guar gum．HPG remains its viscosity and cross linking ability．and considerably decrease its content of insoluble residue．The cost of production has been decreaSed greatly． In order to prepare cationic guar gum，the cationic etherilying agent 3-chloro一2- hydroxypropyl—tfimethyl ammonium chloride(CHPTMA)was synthesized firstly．，Ihc structure ofCttPTMA Was confirmed by IR，MS，NMR and DSC，and the optimum conditions were determined．Then．cationic guar gum Was synthesized wim the cationic etherifling agent CHPTMA and guar gum by organic solvent process，All kinds of influence factors are studied in detail，and the optinlanl conditions were determined．The modified cationic guar gum remains its viscosity，and has low bum residue and hiIgh content ofnitrogen． In this paper，amphoteric guar gum Was also studied,there are two synthetic routes．First phosphate ationic guar gum was prepared；afterwards amphoteric guar gum was synthesized w