含硅有机电致发光材料的合成及性能表征-有机化学专业论文.docx

摘 摘 要 本论文研究了含硅电致发光材料的合成及性能研究，具体内容和结果如下 1．合成了一系列含硅的聚苯硅高分子和含硅聚苯已炔高分子，通过各种分析手 段对合成的化合物结构和性质进行了表征，研究了化合物的荧光性能。 2．合成了含硅的小分子化合物四(B一萘基)硅，用氢谱、碳谱和质谱对它进行 结构的表征，通过TGA测定了化合物的热稳定性，测定了化合物的吸收光谱 和荧光光谱，最后制备了含四(13-荼基)硅的电致发光器件，发现四(B一 萘基)硅是可以做空穴阻挡材料。这为蓝色电致发光器件的制备提供了一种 新的选择。接着又合成了含咔唑的四苯基硅衍生物，通过氢谱和碳谱确定了 化合物的结构，研究了它们的光谱性能，发现它们可以作为蓝色发光材料。 3．我们发现了用Cul催化合成9一(2一噻吩基)咔唑的方法，并对合成的方法 进行了优化，并且用优化后的方法合成了一系列化合物。 我们还合成了三(B一萘基)膦，通过紫外光电子能谱研究了它在金属Ag的 110单晶表面上的电子结构，以及它1l1Zl．q的相互作用。并制备了含三(B一 萘基)膦的OLED，研究了它的器件性能。 关键词：有机电致发光器件，聚苯硅，四(13-荼基)硅，三(D一茶基)膦 UPS，咔唑。 AbstractPoly(phenylene--silane)s Abstract Poly(phenylene--silane)s were constructed by step--growth copolymerization between difimctional Grignard reagents and dichlorodimethylsilane in moderate yields．1 H NMR confirmed the saucture of desired copolymers．GPC showed narrow molecular dispersibility and conceivable molecular weights．Based on thermal gravity analysis and luminescence studies，the synthesized eopolymers wem potentially found to be as emitters in OLED display．And silicon inserted conjugated copolymer was synthesized by Heck reaction with moderate molecular weight．This silicon containing copolymer is thermally stable to 400 oC，while emission of this polymer is blue—shifted compared with polyphenylenevinylene greenish emission． It shows potential application as organic emitter in OLED A new emitting material，retry(f3-naphthyl)silane(TNS)，was synthesized and used as hole blocking material in organic light—emitting devices fOLEDs)．Devices with a configuration of]TO／a—NPB／TNS／Alq3／LiF／A1 have been constructed，where ITO is indium-tin—oxide，Ⅱ一NPB is(4,41-bisIN一(1-naphthyl)-N—phenylamino] biphenyl)，and Alq3 is aluminum tris(8一hydroquinolate)．A high perfomaance blue light OLED was obtained which emits blue light with a peak at 439nm and starts to emit light at 6 V and the luminance Can reach to 3800 cdgm2 at 13 V and 250 n例cm2．And a series of carbazole substituted tetraphenylsilane have been synthesized，which are characterized by 1H-NMR，13C-NMR spectros