海洋水体和海洋沉积物中多环芳烃的高效液相色谱分析方法研究-环境科学专业论文.docxVIP

AbstractPolycyclic Abstract Polycyclic aromatic hydrocarbons(PAHs)，which is a kind of hazmdous substance for its’nondegradable，carcinogenicity，accumulation and nonvolatility characteristics， has external effect on the environment．Due tO its extensive distribution and long duration，it iS hazardous to human’S health．The environmentalists have focused on the problem for a long time，and have invented and developed many analytical methods． But in oHr country，studies mainly focus on PAHs’resource，transfer and distinguish．It still hasn’t a standard analytical method of PAHs．The aim of the study was to develop a rapid analytical procedure for the detection of PAils in seawater and sediment． In the study,7 of the 1 6 EPA PAHs were analyzed．Ensuring the high precision of the detection method beforehand，evaluating the detectors，the extraction solvents and the extraction methods to assess theirs applications for the extraction and analysis of PAHs in seawater and sediment．For HPLC-UV has the advantage of detecting the PAils，it was selected as the detector．On extraction method selectiou，the direct solvent extraction method．the Soxhlet extraction method and山e Ultrasonic extraction method were campared，mad the Ultrasonic extraction method was selected for its quick and simple steps．Then，use the HPLC-UV detector and the Ultrasonic extraction method．7 PAHs standard samples were analyzed tO assess the PAHs qualitative determination and quantitative determination The recoveries of seawater and sediment are：naphthalene 73．嗍and 75．3％，phenanthrene79．2％and78．O％，fluoranthene 88．i％and 80．7％， pyrene 73．8％and 70．2％，chrysene 77．6％and 72．8％．benzo[k]fluoranthene 87．6％and 83．6％，benzo[a]pyrene 120．3％and 110．0％，respectively．The results indicated that the HPLC—UV analytical method is suitable for the analysis ofthe 7 PAils in seawater and sediment．Then seawater and sedfinent samples were analyzed to prove the results． Based 011 the study，the author has developed a HPLC analytical method for PAH