回转窑废轮胎热解油的特性和用途分析及热解模型研究-工程热物理专业论文.docxVIP

塑垦墨兰篓!堂篓鎏墨 塑垦墨兰篓!堂篓鎏墨 一——壹鉴型上竺：：L 摘 ．要 废轮胎的热解工艺以制取热解油、热解碳和热鼹燃气的形式实现能源回收。 拳文的研究对象就是中试回转窑热解所得的主要产物之～热解油。通过不 秘南度全面考察热解油品质，从而反唆出热解温度对热瓣油品质的影响争强转 窑反应器内热解反应的特点。更为有意义的是，通过套面的品质分析可以对热 解油秘寝囊蒋荣合理鳆进行探讨。 丈中首先对不同热解温度下热解油产率进行分析讨论，然后，针对热解油 温质进行了一系窝分橱；通适无紊蕴裁和理化特性酶奢辑，对热解海作鸯壤斡 特性有了一个走致了解；通过实沸点蒸馏分析，得到热姆油作为一种未提炼油 盼馏分分帝，舞为后续蕊解汝馏分霹细入分析提供了髓提；通过牙燕解全渣和 缸窄馏分的FT-IR官能躅分析，对热解油的芳香性、不饱和性有了整体的了解， 并且清楚了热解油中的极性官能团存在型式及其在热解油不同馏分中的分布。 之盛，对热解油按琴瞬馏分进行了更妇八鼹分析。对轻质石脏油馏分敲了 气相色谱分析，时中质以上馏分在族分分析的基础上也对饱和烛和芳烃族分进 行了气相色谱分赞。由此，全面了簿了热解油的族分级成和悒学组成，对石脑 油馏分中高价值BTX芳烃、中质馏分中多环芳烃的存在和随热解温度变化而发 生的含量增减‘部寄了一个清晰的了解。运迂上述分辨鳍暴与文献中不固反应器 热解油特壮的砖比，可以得到毒史回转察热解工艺的特点。并对轮胎热解的化 擘反应过程进行了总绛醴的讨论。 继而，结合辫转窑内的运动与传热执理分榜，以废耱黯化学反应动力学为 基础，建立了废轮胎农回转窑内热解的数学模型，并将计算结果与试验值进行 了黠照。 最后，在全西了解热解油组成及特性的基础上，对热解油的应用前景进行 了细八探讨。分熬簿浊低产量对直接敢为壤辩和高产量跨透一步加工利餍簿个 方面进行。 美键词： 废轮船；回转霉；热解油；菇麟油馏分；芳香烃 浙江人学坝I‘学位论殳 浙江人学坝I‘学位论殳 l矗IIll；Hl{21}／13 5 Abstract The pyrolysis of scrap tires is to achieve energy recovery buy converting tires to oil，char and gas．The focus of this study is the pyrolytic oil derived from the pilot-scale pyrolysis of scrap tires in a rotary kiln The oil was studied in detail from different aspects，the results of which showed the effect of pyrolytic temperatnre on the properties of the oil and the characteristics of the pyrolysis reaction in the rotary kiln reactoE Moreover,buy such analytical work，a foundation for estimation on the application of the pyrolytic oil was laid． The temperature effect on the oil yield WaS discussed at first．Then，analytical work was carried out as follows：the ultimate analysis and physi-chemical analysis of the pyrolytic oil comprised a sketch of the fuel properties of the oil,Then．through the distillation analysis of the oil，the fraction composition of the“unrefined’’oil was known．After that，a general knowledge of the aromaticity and saturation of the hydrocarbons in the oil was provided by the outcome ofthe FT-IR functional group analysis．Also，from the analysis，the form of the polar functional groups and their distribution i