机械合金化制备高熔点、低熔点金属固溶体和化合物的研究-材料科学与工程专业论文.docxVIP

浙江大学硕士学位论文Abstract 浙江大学硕士学位论文 Abstract Mechanical alloying(MA)has been widely used as a non-equilibrium processing technique tO synthesize materials such as extended solid solution,nanocrystalline，amorphous and quasicrystalline materials,via船Vele plastic deformation,fracture and cold—welding induced by ball collision．Alloys composed of refractory and fusible metals are hardly produced by conventional metallurgical methods because of the conspicuous differences in melting temperatures of the components．MA is much superior to conventional metallurgical methods in synthesizing refractory·fusible systems and fusible metals systems． The microstructure evolution of W一16．7at．％In mixture during MA was characterized by means of X-ray diffractometry,differential scanning calorimetry①so)，scanning electron microscopy(SEM)as well as computer simulation．Experimental results indicated that Ws3．311116．7 solid solution Was synthesized by IdA．W83 311116．7 solid solution is stable until it decomposes into W and In at about 600℃． The effects of externally driven mixing favor the alloying of equilibrium immiscible elements，overriding the thermodynamic driving force(positive heat of mix)that would dictate phase separation in equilibrium．Based on the interfacial roughening model，we discussed the formation of the W·In solid solution at a moderate shearing rate under ball milling even though W and In are immiscible element under conventional conditions．Several factors which contribute to the high stability ofW-In solid solution are discussed． 1nle solid·state reaction and microstracture evolution of In203+AI．Sn02+Al and In203／Sn02+AI systems were studied by XP,D and DSC．It Was confirmed that there were no alloys to be formed betwcen equilibrium-immiscible elements Al··Sn and Al··In even under our ball milling conditions．Intermetallic compound InSn4 Was synthesized in the ln203／Sn02+AI system after milling for 12h．InSn4 decomposed,incorporating witll Fe from the milling medium,and transform