活性炭高选择性净化医用一氧化氮中二氧化氮的特性研究-环境工程专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II 得到了制备核桃壳活性炭的最佳工艺参数：壳碱比 6:1，活化温度为 600°C，活化时 间为 1h。该工艺条件下制备的核桃壳活性炭对 NO 中 NO2 的选择性吸附达到 U=0.73, SUNO2 ,NO =32.96，NO2/NO 在吸附的 5.5h 中都维持在 2%左右，比前面研究的四种活性 炭的选择性吸附性能好； （6）用聚乙烯醇制备的成型活性炭对 NO 中 NO2 也具有高的选择性吸附性能。 在进行 6060min 的寿命吸附实验接近结束前(5500min)，混合气体中 NO2/NO 的比值 仍然满足临床医用 NO2/NO5%的要求。 关键词： NO，NO2，活性炭，选择性吸附，表面官能团，核桃壳 PAGE IV PAGE IV Abstract Nitric Oxide (NO) was extensive used in clinical treatment when it was identified as an “endothelium derived relaxing factor”. However, the inhaled NO (iNO) diluting from bottled gas has a little toxic gas of nitrogrn dioxide (NO2) which is also existed in the product of NO starting from air arc discharge. In order to purify the NO2 efficiently, activated carbon was used as the adsorbent to selectively adsorb NO2 in NO. The mechanism of selective adsorption is discussed by the analysis of the pore structure and acid-basic surface functional groups. On the base, an adsorbent having the character of highly selective adsorption of NO2 is developed. The research achievements are as follows: In order to evaluated the adsorption character of NO2 in NO using activated carbon, the assessment equations of adsorption capacity were designed by definite integral principle on the base researches of selective adsorption of NO2 on the four activated carbon (1#, 2#, 3#, 4#). An automatic specific surface area and porosity analyzer was used to analysis the pore structure of activated carbon and the fractal dimension was calculated. The results showed that the adsorbent of 1# and 4# had the highly selective adsorption of NO2 and it related to the highly specific surface. The fractal dimension illustrated that the rough level on the surface of activated carbon hadn’t direct relation with the specific surface. The results from the analysis of Boehm method showed that the surface functional groups on adsorbents were mainly acidic groups but little basic groups; 2# and 3# were mainly basic groups and acidic groups can hardly be