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ABSTRACT
Icing is a beautiful phenomenon in nature, which can not only brings the enjoyment of vision, but also may result in inconvenience to peoples life, even disaster. By virtue of their unique surface wettability, superhydrophobic materials show great application prospects in the field of anti-icing and the related researches have become a hot topic in recent years. In this thesis, superhydrophobic surface (coded as SHS) was fabricated on aluminum alloy substrate via a simple chemical etching and subsequent surface passivation. The anti-icing behaviors on SHS and the control samples (i.e., hydrophilic and hydrophobic surfaces on Al alloy, coded as HIS and HHS, respectively) were investigated on the self-designed experimental platform. Specifically, the freezing of sessile water droplet, the shape of the so-frozen ice droplet, the formation of frost on the so-frozen ice droplet, and vertical adhesion strength between ice and the substrates, were analyzed in detail. Main research contents and results were as follows:
SHS on Al alloy and control samples (i.e., hydrophilic and hydrophobic surfaces on Al alloy) were fabricated. Static contact angle (SCA) and sliding angle (SA) for SHS were measured to be 164.6° and 4°, respectively. For hydrophobic and hydrophilic samples, SCA was 116.5° and 57.1°, while the contact angle hysteresis (CAH) is 20° and 45° respectively. Surface morphology observations revealed that the surface on superhydrophobic sample was uneven with rough micro-structure; however, for hydrophobic and hydrophilic surfaces, they were much more smoother. The stability of SHS was also invetigated. The change in SCA and SA for SHS was not obvious after the sample being exposed to air conditions (25 °C) for 30 days or ultrasonicated in ethanol for 45 min.
The freezing of sessile water droplet on cold surface was investigated. Experimental results showed that such a freezing process could be divided into two sub-processes, i.e., homogeneous cooli
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