茂金属催化剂用于间规聚丙烯制备的研究-化学工程专业毕业论文.docxVIP

摘 摘 要 本论文研究了间规选择性茂金属催化剂(c，。HBPh。CMePhC。H4)ZrCI。的合成制 备条件，并对其催化丙烯间规聚合的影响因素进行了探讨和分析。 制备催化剂(c，3l{6PhzCMePhCsH一)ZrCl：关键步骤为与金属的络合反应。通过 对在四氢呋喃、二氯甲烷、戊烷、．甲苯和乙醚等溶剂中进行与金属络合反应的产 率比较得知，乙醚为该反应比较恰当的溶剂。利用该络合物与助催化剂MAO进行 聚合反应，在比较低的压力下得到的聚丙烯的间规度)80％，熔点为130。C。络 合物和聚丙烯都通过了IR，1H NMR，EI-MS spectra和DSC等测试。 讨论了聚合温度、聚合溶剂、[A1]／[zr]对聚合反应体系的影响。研究了聚 合反应的动力学，分析了反应中随聚合时间反应速率的变化，证明了反应过程的 不均匀性，为该项目的中试提供了参考。研究了sPP的热性能，sPP的热稳定性 强于iPP，由于不同的热处理过程可能会导致形成不同的晶型，并引起其相互转 变，导致双熔点的出现。由此分析了等温结晶过程和非等温结晶过程双熔点的变 化。 关键词：间规，聚丙烯，聚合，茂金属 In In this thesis， Cs—symmetric syndioSpecific metalloncene catalyst， (C13H6Ph2CMePhC5H4)ZrCl2，was synthezied and WaS used for preparing the syndiotaetic polypropylene(sPP)． The important role of the solvent during the course of preparation of catalyst complex was studied．It was found that the ether was much mofe suitable solvent for the preparation of catalyst than other solvents．By using this complex and the coeatalyst，methylalumoxane(MAO)，syndiotactie polypropylene(sPP)with syndiotacticity index(SI)80％，melt point 130*Cwas pmpared in the condition of low pressure．The metallocene complex and sPP have been characterized by means of 讯．1H NMR,El-MS spectra and DSC． The different conditions such as temperature，solvent and[灿】／【Zr]have a great influence upon the process of polymerization．Through the kinetic curves，it was showed that the intensity of the reaction could be controlled by decreasing the temperature of the polymerization reaction．The thermal behaviors included thermal stability and the double melting peak phenomena were studied based on the sPE It was confirmed that sPP was quite stable in air and the double melting peak WaS related to the different crystal of sPP Furthermore the nonisothermal and the isothermal crystallization were investigated by DSC． KEYWORDS：Syndiospecific，Polypropylene，Polymerization，Metallocene 独创性声明本人声明所呈交的学位论文是本人在导师指导下进行的研究工作和取得的 独创性声明 本人声明所呈交的学位论文是本人在导师指导下进行的研究工作和取得的 研究成果，除了文中特别加以标注和致谢之处外，论文中不包含其他人已经发表 或撰写过的研究成果，也不包含为获得鑫茎盘壁或其他教育机构的学位或证 书而使用过的材料。与我一同工