抗氧化剂微胶囊的制备及其控制皮革中六价铬含量的研究-皮革化学与工程专业毕业论文.docxVIP

郑州大学硕士学位论文Abstract 郑州大学硕士学位论文 Abstract Sexivalent chromium(Cr(VD)in leather is systemic problem，which includes the formation；determination,and prevention of sexivalent chromium．Both raw hides or skins and leather chemicals may lead to the formation of sexivalent chromium． Tanning process of leather making may affect the formation of sexivalent chromium as well．The toxicity of sexivalent chromium is one hundred times more than of that of trivalent chromium(C“ⅡD)．Carcinogenesis and damage to the skins may be caused by sexivalent chromium．So the study on the formation,determination；and prevention of sexivalent chromium in finished leathers is one of the great problems facing the leather industry．In the recent years，more and more strict regulations are applied for the soluble chromium in leathers by Western Europe and Australia． Generally,the need for soluble chromium in leathers is less than 5 ppm．In some more strict regulations，the need may be less than 2 ppm． Formation cause of sexivalent chromium iS studied in this article．The result of experiments shows：Content of sexivalent chromium increases more than three times when leathers are heated，and extending being heated time and rising the being heated temperature are equivalent in the formation of sexivalent chromium content in leathers．Content of sexivalent chromium rises as pH rises，and content of sexivalent chromium doesnt change obviously when pH is 7．5-8．0．Relative humidity also influences the content of．sexivalent chromium and content of sexivalent chromium decreases greatly when relative humidity is 20％一40％． Three ways are used to prevent the formation of sexivalent chromium,which are using vegetable tannin to retan,adding Mg+into extracting liquor,and adding antioxidant into leathers．Such materials as vitamins，tea polyphenols，synthesized antioxidant，reducing agent，phytic acid and etc are used to prevent the formation of sexivalent chromium．Content of sexivalent chromiuln in leathers is reiIuced to 2．Oppm by vi