铝热还原法制取CuCr合金渣系粘度的测量及其模型研究-有色冶金专业毕业论文.docxVIP

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铝热还原法制取CuCr合金渣系粘度的测量及其模型研究-有色冶金专业毕业论文.docx

铝热还原法制取CuCr合金渣系粘度的测量及其模型研究摘要 铝热还原法制取CuCr合金渣系粘度的测量及其模型研究 摘要 CuCr是一种很好的触头材料。在采用铝热.电磁铸造法制备铜铬合金的过程中, 由于生成物氧化铝凝固点较高,在金-渣分离时先凝固,造成液态铜铬无法与渣很好 的分离。本文意在通过加入添加剂氧化钙、氧化镁等物质使渣相熔点降低,并有较 小的粘度。欲使渣相与液态合金在较短的时间内迅速分离,形成均匀的金属相和渣 相,需要了解渣的粘度。以往研究的渣系大部分含有二氧化硅,对铝热反应渣系的 粘度研究的比较少。而且,高熔点渣系的粘度测量是很难进行的,而且需要耗费大 量的人力、物力和财力。在这种情况下,粘度估算提供了很有价值的理论依据。 /本文简述了粘度测量方法、粘度的估算原理;对铝热还原-电磁铸造法制备铜铬 合金的渣系进行了选择,选择合适的添加剂。采用内旋转圆柱法测量了Alz03--CaO 和A1203--CaO--MgO两渣系共五个渣样的粘度。 本文通过测量和计算得出以下结论: (1) 在A1203一Ca0二元系中,当温度高于1460。C时,组成在共晶点附近的熔渣 粘度低于0.5Pa.s,属于流动性较好的渣。 (2) 在A1203一caO—M90的两个共晶点处,氧化钙较多的,粘度较低,在温度 达1400。C时,粘度已低于0.2 Pa.S,当温度等于1500C时,粘度已经小于0.03 Pa.S。 (3) 本文采用模型n=等等exp(篑}),并用相关文献的实验数据计算出A13+ 和ca2十的作用系数L, 并计算了鸽03-cao渣系的粘度,计算结果与实验数据吻 合较好。 (4) A1:o,一c。o体系中加入适量的添加剂氧化镁,能够降低猹垂篁查逛。)夕’/ 关键词熔渣亍添加剂,《藿二玉蓍延麴董二丑翌塑呈段殳。 一 一II— 查i!垄主墅主堂焦堕墨 查i!垄主墅主堂焦堕墨 些!墅生堕 Research on Measurement and Modeling of the Viscosity of the Slag in the Preparing CnCr Alloy by the Thermit and Electromagnetic Casting Abstract CuCr is pretty good contact material.In the research on preparing CuCr alloy by the thermit and electromagnetic casting,becatlse A1203 has high melting point,the separation between the alloy and slag is very difficdt.The intention in this paper is to get the slag with a low melting point and low viscosities bY adding addictive such as calcium oxide and magnesia etc.It is important to know the knowledge ofviscosities in order to separate metal from slag quickly and effectively.However,there are a few data about the viscosity ofa family ofAl203 slag without silicon dioxide.It is very difficult and costly to carry out the measurement of the viscosities of some slags which have high melting points, therefore,it is very imperative and significant in theory to estimate and model viscosities ofthese slags. The measuring methods and the estimating principle of viscosity are described simply in this paper.The slag systems that are appropriate

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