氯烃用高效复合热稳定剂的研究-应用化学专业毕业论文.docxVIP

；鲁女^事硕士毕业论文摘要 ；鲁女^事硕士毕业论文 摘要 ，’ l氯烃产品受热能缓慢的发生分解反应，放出HCI，而放出的HCI又能诱导 和促进氯烃产品的进一步分解，使原有的产品品质降低。少数氯烃产品甚至在 常温下也有分解现象发生。添加热稳定剂是解决氯烃产品分解的行之有效的办 法。单一组份的热稳定剂效果不佳，而目前使用的复合热稳定剂用量太，综∥ 成本高，另一方面随着时间的延长，热稳定性能有所下降。针对上述问题，，本 文主要进行了以下几个方面的工作： 一、在文献调研和以往工作的基础上，充分了解氯烃的热分解机理；了解 各类热稳定剂的作用机理及其使用局限性；了解目前热稳定剂的研究进展和使 用情况，从而设计出高效复合热稳定剂的基本构成。根据各组份在复合热稳定 剂中所起的作用，将复合稳定剂分成主稳定剂和辅助稳定剂两部分。 二、在实验的基础上，确定了以乙二醇二缩水甘油醚为主稳定剂，以BCZ 稳定剂、脱氢乙酸、原甲酸三乙酯为辅助稳定剂的配方组成。通过正交实验， 最终确定了复合热稳定剂的组成及相对含量；确定了乙二醇二缩水甘油醚合成 的最佳工艺条件。 三、对复合热稳定剂的作用机理进行了初步探讨，通过实验，研究了复合 热稳定剂的协同效应。 四、对乙二醇二氯代二丙醇醚合成反应动力学进行了研究。 关键词：复合：热稳定菊_机理，协哥《盘，动另车 K ^ 塑!!!堡圭望些堕奎Abstract 塑!!!堡圭望些堕奎 Abstract Chlomparaffms gives out HCl when it is heated that can induce and accelerate it to do，SO it loses o姆nal properties．Sometimes,it also gives out HCI eVerl at normal atmospheric temperature．Adding heat stabilizer to it is the best measures in order to prevent to decompose．Heat s诅bifizer of only one kind of ingredient have not meet the needs ofpeople．But present composite heat stabilizer is not ideal．For the sake ofresearching a kind ofefficient composite stabilizer，the research plan of this paper is as following： 1．Based ort the literature leview and experimental resultS，mechanism of the heat decomposition for choloparaffins is complete analyzed．At the salne time mechanism and limitations for plenty of heat stabilizers arc understood．According to function of respective ingredient,composite heat stabilizer is composed of two kind ofingredient：main and auxiliary stabilizer． 2．Based on the experiment,ethylene glycol diglycidyl ether is regarded拈 main stabiliz目．．and BCZ stabilizer,dehydroacetic acid and triethyl oilhoforrnatc a糟 regarded as attxiliary stabilizer．．By e．xperiment,ingredient of composite stabilizer is affirmed．Besides,the best teclmotogical condition of synthetic ethylene glycol diglycidyl ether is also affirmed． 3．Mechanism of action and synergistic effect of comppsite stabilizer is preliminarily studied by experiment． 4．Synthetic kinetic equation of ethylene