空心乳液的合成及其性能研究-高分子化学与物理专业毕业论文.docxVIP

空心乳液的合成与性能研究 空心乳液的合成与性能研究 河北工业大学硕士学位论文 河北工业大学硕士学位论文 SYNTHESIS AND PROPERTIES OF HOLLOW POLYMER EMULSION ABSTRACT Hollow is a special core-shell latex emulsion, generally it refers to prepared by emulsion polymerization with a cavity inside .Because of the hollow latex hollow structure, it has very different refractive index of light between shell polymer and the air cavity , scattering of incident light can be effective, which has a good covering effect and excellent whiteness. Multiple emulsion as an alternative to the current titanium hollow white plastic pigment used in paint, water-based inks, the field of low-weight coated paper. Moreover micro-capsules are also used as materials and UV additives. Since its inception in the eighties of last century, a good prospect of hollow latex aroused extensive attention. Semi-continuous dropping method was adopted to prepare hollow latex particles with moderate size and enough rigidity. Methyl methacrylate (MMA), butyl acrylate and methacrylic acid (MAA) were first copolymerized as seed latexes, and then MMA, MAA and divinyl benzene (DVB) were carried out to prepare hydrophilic carboxylated core latex particles consequently. On the basis of the core latex, the hydrophobic shell was then formed with styrene, MMA and DVB. Finally, the hollow emulsion were obtained by alkalization treatment of the core-shell latex particles. The effects of reaction temperature, MAA, emulsifier, cross-linked monomer, core/shell ratio and alkali treating on the emulsion stability and morphologies of hollow latex were investigated. The morphologies and particle sizes of hollow latex particles were characterized by TEM. The results show that the structure and properties of hollow emulsion is effected by the diameter and number of seeding emulsion, dosages of ii iii iii core/shell monomer, alkali treating, when core/shell ratio was 1:8, and counteract degree was 40%, the covering performance of hollow emulsion was the best and if it was more than