镁合金化学镀镍工艺研究-应用化学专业毕业论文.docx

沈阳理工大学硕士学位论文 沈阳理工大学硕士学位论文 Abstract Magnesium alloys can be widely used in aerospace,automotive,electronics and other fields, but the corrosion potential of magnesium alloys is extremely low, greatly limited the application of magnesium alloys. The problem can be solved by electrolss nickel plating.Corrosion factors of magnesium alloys in plating solution which is the simplest electroless plating nickel formulation was studied by the method of corrosion weight loss.The results show that corrosion speed of magnesium alloys is fast which is influenced by pH value, temperature, sulfate radical and nickel radical,but corrosion speed of magnesium alloys is slow when it is immersed into distilled water or sodium hypophosphite solution.So,three processes of electroless nickel plating on magnesium alloys directly were studied in this paper. Pretreatment of magnesium alloys which is the first process were studied, acid pickling formula and activation formula were defined by contrast experiment.The properties of electroless plating Ni-P were detected by SEM, XRD and electrochemical polarization curves.The results indicated that the Ni-P coating is very meticulous and uniform,and the structure of Ni-P coating is amorphous,electrochemical polarization test indicated that corrosion potential of magnesium alloy was improved about 1.1V,and corrosion current density dropped obviously. Electroless plating nickel solution using nickel hydroxide as main salt was studied which is the second poccess.The best formula was defined by single factor experiment and orthogonal experiment.The beginning growth procedure of electroless plating nickel was tested and analyzed by SEM and EDS,procedure of growth can be divided into two stages,the first stage is exchange reaction between nickel ions and magnesium,the average activation energy is about 103.3KJ·mol-1;the second stage is Ni-P co-deposition reaction,the activation energy is about 78.3KJ·mol-1.The adhesion of magnesium