磷光及热致延迟荧光主体的合成及性质研究-应用化学专业毕业论文.docxVIP

磷光及热致延迟荧光主体的合成及|生质研究Synthesis 磷光及热致延迟荧光主体的合成及|生质研究 Synthesis and Properties of Phosphorescent and Thermally Activated Delayed Fluorescence(TADF)Host Materials Abstract Electrophosphoresecnt and thermally activated delayed fluoresecence(TADF) materials can fully harvest both singlet and triplet excitons in Organic Linght-emitting Diodes(OLEDs)to achieve the internal quantum efficiency of unity．Because of their excellent efficiency merits，they have always been the the hotspots in OLED．In order to avoid the aggregation quenching and exciton annihilation of triplet excitons and fulfill the efficient utilization of electric excitons，light—emitting layers featuring host—guest system should be applied in both phosphorescent and TADF devices． The ideal host materials should have high triplet energy，suitable HOMO／LUMO energy levels．certain charge transporting abilities and fine spectral overlap、航th luminophers．Bipolar host materials possessing both hole and electron transpoting abilities could not only meet the above requirements，but also banlance the hole and electron fluxes which is superior to unipolar hosts and proved benefical to expand the charge recombination zone and thus improve the luminous efficiency and alleviate the efficiency roll-off．So in this thesis，by adopting the electron·withdrawing pyridine or triazole groups and varying the species of electron-donating units and their molar ratio to acceptor ones，we developed a series of phosphoresecent and TADF host materials．Details are as follows： (1)Small and solution—processible bipolar host materials．Four novel hosts，namely G1CzPy，G1CzTz，G2CzTz and G2CzPy，were developed by combining 1 generation or 2 generaton oligo-carbazole dendrimers with electron-withdrawing units，pyridine or triazole， in the linkage form of D一7c—A．The separation of HOMO and LUMO orbitals confmned their bipolar transporting abilities．Moderate extent of 7c conjugation in these molecules not only facilitated the charge transporting，but also gu