预固化工艺对玻璃纤维环氧树脂复合材料界面及弯曲性能影响.docVIP

预固化工艺对玻璃纤维/环氧树脂复合 材料界面及弯曲性能影响 冯古雨 曹海建 周洪涛 钱坤 生态纺织教育部重点实验室江南大学纺织服装学院 南通大学纺织服装学院盐城工业职业技术学院纺织 服装学院 摘要： 以2400tex无捻玻璃纤维粗纱为原料，在SGA598型三维织机上制备岀一种三维 浅交弯联机织复合材料预制体，以环氧树脂E51和固化剂聚醸胺W11R-I1023以质 量配合比3 ： 1的比例组成树脂体系，使用真空灌注成型的方法制备玻璃纤维/ 环氧树脂复合材料。真空灌注后，将模具与未固化成型的复合材料进行不同时长 的预固化处理，制备出预固化工艺不同的三维浅交弯联机织复合材料。通过万能 强力仪、扫描电子显微镜对该复合材料的弯曲力学性能及破坏断面微观形貌进行 考察，分析不同的预固化工艺对复合材料界面及弯曲性能的影响。实验结果表明: 当预固化时间为120min时，制得的复合材料弯曲强度达到675MPa,弯曲强度较 传统恒温热固化工艺提高了 75. 8%,改善效果较为明显。 关键词： 预固化工艺;复合材料;界面性能;弯曲性能; 作者简介：冯古雨（1992-），男，硕士，主要从事纺织复合材料的制备及性能 研究。 作者简介：钱坤（1963-），男，教授，博士生导师。主要从事轻量化复合材料 的制备及应用。 收稿日期：2016-06-02 基金：“十三五”国家重点研发计划项冃（2016YFB0303205） Influence on mechanical property and interface of E-glass fiber/epoxy resin composite by precuring Feng Guyu Cao Haijian Zhou Hongtao Qian Kun Key Laboratory of Eco-Textile of Ministry of Education, Jiangnan University; Abstract： A three-dimensional (3D) curved shal1ow~crossing 1inking :reinforcement was prepared used glass roving of 2400 tex by 3D weaving machine modeled SGA598. The resin matrix was composed of epoxy resin E51 and polycther amine WHR-H023 in a mass ratio of 3 ： 1, 3 Dcurved shallow-crossing linking woven composite was then made from surface—treatment reinforcement and resin matrix by VART method. Precuring process with different periods were applied on the compos it es. Universal material testing machine and secinning electron microscope (SEM) were used to charactcrized the influence of precuring process on the interface between reinforcement and resin and flexural property. The results showed that flexural stress of composites remained unchanged after increase fi rst with precuring process periods in creased. Compared with the composites without through precur ing process, with 120 min precuring process, the flexural stress was increased by 75. 8%. The interface between reinforcement and resin was improved with increasing precuring process periods. Keyword： precuring process; composites; interface; flexural property; Received： 2016-06-02 三维浅交弯联机织复合材料是近年来出现