锂离子电池正极材料层状镍钴锰酸锂的制备及其表征-材料物理与化学专业论文.docxVIP

硕士学位论文 硕士学位论文 ABSTRACT ABSTRACT The precursors NixC01．2xMnxC03(x=3／10，l／3，4／10)were prepared by CO—precipitation，followed by preheat treatment in air,and then reacted with lithium carbonate at hi曲temperature to obtain the homogeneous layered oxides LiNixC01．2xMnx02(x=3／lO，1／3，4／lO)．ne structure characteristics and electrochemical properties of the prepared samples were tested using XRD，SEM，cyclic voltammetry and constant-current measurements．The main conclusions were as following： 1．The composition of Ni，Co and Mn plays an important role in determining the electrochemical performances of LiNixCoi．2xMnx02 (x=3／10，1，3，4／10)：(1)C03+Can effectively stabilize the layered structure of t11e composites and inhibit the disorder cationic distribution of sites 3a and 3b．The cell parameters a．c and the unit cell parameter decrease with the increase of the CO content，resulting in good rate electrochemical performances；但)The cell parameters a and c increase with the increase of the Ni2+content．which increases the reversible lithium-intercalation capacity；(3)Mn4+do not participate in the redox reactions in the process of Li intercalation and deintercalation as electrochemical non-active substances and supports the layered structure，which improves the cyclic performances． It Was found that the combination properties of LiNil／3COl／3Mnl／302 are best among them． 2．The primary particles of the LiNixC01．2xMnx02(x=3／10，1／3，4／10) are size—homogeneous and primarily sphere—like with good mobility and machinability．The microstructure patterns of the primary particles and the secondary aggregates Call be controlled through adjusting the heat-treatment parameters． 3．The layered ternary lithium nickel cobalt manganese oxides LiNixCoI．2xMnx02(x=3／10，l／3，4／10)were found to have good electroche— mical properties with the optimally synthesise temperature of I 000*C．It Was found