磷酸银及其复合光催化剂的制备与性能研究-材料学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 万方数据 万方数据 Abstract To further improve the photocatalystic perfrmance of Ag3PO4 semiconductor, we focus on the morphology control synthesis of Ag3PO4, and the development of Ag3PO4 based semiconductor composites. In this thesis, single-crystalline Ag3PO4 nanowires were synthesized at room temperature for the first time via a facile one-step precipitation reaction and novel Ag2O/Ag3PO4 composite were fabricated by ion-exchange method. The phases, morphologies, and microstuctures of the prepared samples were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and selected-area electron diffraction (SAED). The optical absorptions and photocatalytic activities of the these samples were measured by UV-vis diffused reflectance spectrometer. Single-crystalline Ag3PO4 nanowires were synthesized via a facile one-step precipitation reaction at room temperature, during which ethyl alcohol was used as the solvent of the reaction system, phosphoric acid as the phosphorus source and PAA as a capping reagent. The SEM and TEM images showed the uniform nanowires were grown from the four cones of tetrapods and were about 70 nm in diameter and 10 μm in length. SAED results revealed that these nanowires were single-crystalline and grew with preferred [111] orientation. It’s found that PAA plays an essential role on the formation of the nanowired morphology, which may due to its selected adsorption on {110} caused by the large amount of carboxyls in the molecular chain of PAA capping agent. Single-crystalline Ag3PO4 nanowires exhibited higher photocatalytic activity than spherical Ag3PO4 particles for the degradation of RhB and MB under visible light irradiation, which may be due to the increased surface area and the unique one-dimensional nanostructures Moreover，novel Ag2O/Ag3PO4 composite was fabricated by ion-exchange method between Ag3PO4 and NaOH at room temperature. UV-vis results