硫化物半导体发光纳米晶和稀土荧光纳米颗粒的制备、表征及应用分析-材料物理与化学专业论文.docxVIP

华 华 中 科 技 大 学 博 士 学 位 论 文 IV IV the crystal phase, morphology, optical, photothermal properties of these as prepared CuS nanoparticles. Good performance of the infrared light based photothermal effect prompted us to apply it to women cervical cancer cells (Hela cell) in vitro photothermal ablation treatment upon a infrared light with a wavelength of 808 nm. The assessment of cytotoxicity and thermal ablation effect of these CuS nanoparticles shows that CuS nanoparticles is very promising to enhance the treatment effect of cancer in photothermal albation therapy due to their excellent thermal properties and lower toxicity. In the fourth chapter, we focus on the research of water soluble cerium oxide (CeO2) nanoparticles. We prepared water soluble CeO2 nanoparticles by a simple wet chemistry method firstly, and later move on to the study of gene toxicity effect of CeO2 nanoparticles on human epithelial cells. The sister chromatid exchange and single cell gel eletrophoresis investigation reveals that the gene toxicity of CeO2 nanoparticles is low and it’s proper to apply the CeO2 nanoparticles in ophthalmic research. In the fifth chapter, we mainly paid our efforts to synthesis and characterization of CePO4:Tb/LaPO4 core-sheathe fluorescent nanowires. We first synthesized monodisperse CePO4:Tb nanoparticles, and second, allied them in one direction, finally coating the outside of the aggregation with LaPO4 by follow-up reaction, resulting the CePO4:Tb/LaPO4 fluorescent nanowires.The morphology investigation and fluorescence enhancement proved the successful coating of LaPO4 layer. The successful synthesization of CePO4:Tb/LaPO4 shows that the rare earth phosphate nanowires can also be obtained under ambient environment, and this simple synthesization method and opticals properties in favor of rare earth phosphate nanowires in comercial production and fabrication of solid state lighting and optoelectronic devices. Key words: semiconductor nanocrystals; rare earth nanop