无线磁弹性传感器检测铀的新方法研究.pdf

这些发现，建立了应用磁弹性传感器无线传感测定铀(Ⅵ) 的新方法。研究了酸度、 试剂等多种因素对测定的影响。在铁(Ⅲ) 、铁氰化钾和硫酸浓度分别为 0.01、 0.01 和0.5mol/L 的条件下，测定铀(Ⅵ) 的线性范围为0.12~14.1μg/mL，检出限为 0.02 μg/mL 。应用该方法测定了实际样品中的铀(Ⅵ) ，回收率为96.7 ~ 104.0% 。 关键词：铀；无线磁弹性传感器；催化；沉淀；水解；抑制 - IV - Determination of uranium using wireless magnetoelastic sensors Abstract In this paper, we mainly studied several new methods for the determination of trace uranium by using wireless magnetoelastic sensor technique. In the introductory part of this paper, the property, application and fatalness of uranium, and the research development in the determination of trace uranium were outlined. Then the basic structure and work principle of wireless magnetoelastic sensors were introduced, and the research development in the application of the sensors was also reviewed. In Chapter 2, a wireless sensing method for the determination of uranium (IV) was described. we found that mercury (II) can catalyzed the precipitation reaction between potassium ferrocyanide and potassium ferricyanide, and uranium (IV) can inhibited the catalysis of the mercury (II). The resultant precipitates deposited on a thick-film ribbon-like magnetoelastic sensor can change the resonance frequency of the sensor. Based on these findings, a new method is developed for the determination of trace uranium(IV) by using a wireless magnetoelastic sensor based on the precipitation inhibition. The magnetoelastic sensor technique has a unique advantage in that wirelessly detect resonant frequency shifts of a magnetoelastic foil in response to differences in the foil mass. The influence of manifold variables on the determination is investigated in details. When the