焦化废水制备水煤浆及燃烧特性研究.docxVIP

中国工程热物理学会 固体燃料燃烧 学术会议论文 编号：184211 焦化废水制备水煤浆及燃烧特性研究 汪逸，陈聪，徐发锐，刘建忠* （浙江大学能源清洁利用国家重点实验室，浙江 杭州 310027） （Tel: 0571Email: jzliu@）? ?基金项目：国家重点研发计划项目(No.2016YFB0600505) 作者简介：汪逸（1994—），男，硕士研究生，E-mail：sunsfrank@126.com；*通讯作者：刘建忠，教授，E-mail：jzliu@ 摘要：利用焦化废水、去离子水与神华煤制备水煤浆，进行了成浆性、流变性、稳定性以及燃烧特性的实验。结果表明，焦化废水水煤浆的定粘浓度能达到60.5%以上，比去离子水低0.5-1.5%左右，但假塑性特征更明显；NNO和NDF的分散效果更好；与去离子水水煤浆相比，焦化废水水煤浆的稳定性更好；焦化废水水煤浆的着火温度、燃尽温度更低， 燃烧特性参数更高，性能更优。利用焦化废水制备水煤浆，不仅能够实现废水的资源化利用，而且能够提高燃烧特性。 关键词：水煤浆；焦化废水；添加剂；成浆性能；燃烧特性 Research on slurryability and combustion characteristics of coal-coking wastewater-slurry Wang Yi, Chen Cong, Xu Farui, Liu Jianzhong* (State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China) Abstract: In this paper, experiments on slurryability, rheological properties, stability and combustion characteristic of coal water slurry, which is made by coking wastewater, deionized water and Shenhua coal are studied. The results show that the solid concentration of coal-coking wastewater-slurry(CCWS for short) can be higher than 60.5%, which is 0.5-1.5% lower than coal water slurry(CWS for short) but pseudoplastic is more obvious. The dispersion effect of NNO and NDF is better. Comparing with CWS, the stability of CCWS is better. And CCWS has lower ignition temperature and burnout temperature, higher combustion characteristic parameters and better performance in combustion. The application of coking wastewater for production of coal water slurry not only realized the resource utilization of wastewater, but also improves the combustion characteristic. Keyword: coal water slurry; coking wastewater; additives; slurryability; combustion characteristic. 0前言 焦化废水是在焦炭炼制产生的高浓度有机废水，其中主要污染物为酚类（＞50%），还包括氨氮、硫氰化物、氰化物、多环芳烃及含氮杂环化合物等，属于典型有毒难降解有机废水[1]。目前针对该废水，国内主要采用以碳、氮循环为核心的生物处理方法[2]。这些方法虽然能够有效去除大部分有机物和氨氮，但是仍然存在前端厌氧单元受毒性抑制强以及氨氮排放难以达标的过程[3]，同时废水中