锰基催化剂上nox脱除的研究-化学工程与技术专业论文.docxVIP

北京化工大学硕士学位论文左右，N2选择性在90％以上，且具有良好的抗H20和S02性能。通过表征 北京化工大学硕士学位论文 左右，N2选择性在90％以上，且具有良好的抗H20和S02性能。通过表征 发现，M003在M／1Zr上高度均匀分散，在中高温下具有很强的氧化还原 能力。DRIFTS分析表明M003的添加增强了催化剂的酸性，继而有利于 反应物NH3的吸附于活化，产生更多的活性氨物种，同时抑制了硝酸盐 物种在催化剂表面的生成，加速了NH3一SCR反应的进行，从而提高了催 化剂的脱硝性能。 关键词：氮氧化物，选择性催化还原，球状MnCeOx，M003／MnZr Ⅱ 万方数据 ABSTRACTSTUDY ABSTRACT STUDY oN THE NOx REMOVAL OVER MANGANESE-BASED CATALYSTS ABSTRACT DeNOx catalyst plays an important role in the selective catalytic reduction of NOx by NI-13(／Ⅲ-13一SCR)and Mn—based catalysts show an excellent NI-13一SCR activity．In this research，we develop an active spherical MnCeOx catalyst for the low temperature NH3一SCR of NOx by changing the catalyst morphology．And M003／MnZr catalyst，which demonstrated to be active for the NH3一SCR of NOx，has also been developed．The structures of these catalysts were characterized by BET,XRD，XPS and H2一TPR．DRIFTS were used to reveal the reaction mechanism over these catalysts． The new types of spherical MnCeOx catalysts were prepared by the hydrothermal method．It Was found that 9Mnl Ce catalyst showed good NO oxidation activity,satisfied NH3一SCR activity and high tolerance to H20 and S02．In the temperature range of 75-200℃，nearly 1 00％NOx conversion Was achieved．Even in the case of H20 and S02，the NOx conversion Was around 90％．Moreover,the alkali metal just showed a weak poisoning effect on the activity．Based on the characterization，it was found that spherical 9Mnl Ce catalyst had high specific surface area,large amounts of surface oxygen and HI 万方数据 北京化工大学硕士学位论文good 北京化工大学硕士学位论文 good redox property．The DRIFTS revealed that there were more acid sites existed on the catalyst surface． Different loading of M003 were added into／诋lZr catalyst prepared by hydrothermal method by impregnation method．The added M003 greatly improved the activity and the selectivity to N2 of MnZr catalyst．Both the NOx conversion and the selectivity to N2 in the temperature range of 250—400。C are over 90％on the 1 5MoMnZr catalyst．It also showed high re