PHBV纳米CaCO3共混物的热性能和力学性能-Journalof.PDF

第29 卷第7期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol29, No. 7 2 00 8 年 7 月 Journal of Northeastern U ni ersity( Natural Science) Jul. 2 0 0 8 PHBV/ CaCO 3 1 1 2 徐孝旭, 张宝砚 , 富露祥 ( 1. , 110004; 2. , 110142) : - - ( PHBV) / CaCO 3 , DSC, T GA, DMA , , PHBV , CaCO PHBV 3 , CaCO 5% , 3 : PHBV; CaCO ; ; ; 3 : O 631. 1 : A : 1005-3026( 2008) 07- 106 1-04 Thermal and Mechanical Properties of PHBV/ CaCO Blends 3 1 1 2 X U X iao-x u , ZHA N G Bao-y an , F U L u-x iang ( 1. School of Sciences, Northeastern Uni ersity, Shenyang 110004, China; 2. School of Material Science and Engineering , Shenyang Institute of Chemical T echnology, Shenyang 110 142, China. Correspondent : XU Xiao-xu, E-mail: 3x . 931 @ 163. com) Abstract: PHBV/ CaCO blends were prepared by w ay of banbury ing, and the thermal and 3 mechanical properties of the blends thus prepared were in estigated by means of differential scanning calorimetry ( DSC) , thermogra imetric analysis ( T GA) , dynamic mechanical analysis (DM A) , tensile tester and rotary rheometer. The results showed that the atmosphere does not affect the thermal stability of PHBV blends, and a certain amount of CaCO nanoparticles as 3 additi e hardly affect the glass transition temperature and thermal decomposition t