高浓度kcl溶液及h2sco对2共存体系中缓蚀剂协同效应的研究.docx

北京化工大学硕士学位论文(1)三种阳离子表面活性剂的表面活性随疏水烷基链长度的增加而 北京化工大学硕士学位论文 (1)三种阳离子表面活性剂的表面活性随疏水烷基链长度的增加而 增强，缓蚀性能与表面活性呈正相关关系，表面活性越强，缓蚀性能越优 异，其表面活性和缓蚀性能强弱顺序为CTABTTABDTAB。 (2)PB分别与DTAB、TTAB、CTAB复配，均显示出良好的缓蚀 协同作用，其中PB与CTAB之间的缓蚀协同效应最为明显，复配组合的 缓蚀性能强弱顺序为PB+CTABPB+TTABPB+DTAB。 (3)PB优先吸附于碳钢表面的HS‘层，但这层吸附膜存在一定的缺 陷，阳离子表面活性剂的加入不仅提高了PB的分散性、润湿性和渗透性， 还起到协同吸附的作用，在碳钢表面未吸附的活性空位继续吸附，使吸附 膜层覆盖度提高，有效抑制碳钢的腐蚀。 关键词：KCl，H2S／C02，缓蚀剂，阳离子表面活性剂，缓蚀协同效应 万方数据 RESEARCH RESEARCH oF SYNERGISTIC CORROSION INHIBITIoN EFFECT IN HIGH CoNCENTRATIoN KCl SoLUTION AND H28／C02 COEXISTENT SYSTEM ABSTRACT Corrosion problem exists widely in the world，and it has brought great harm to economy,environment and public security．Among many corrosion protection measures，corrosion inhibitors have the advantages of low-cost， quick effect and SO on．However,the individual inhibitor Can no longer meet the requirements of corrosion protection work．More and more scholars devoted to the study of the synergetic inhibition effect of the composite system and it has long been an important development direction of corrosion inhibitors． In this paper,synergistic corrosion inhibition effect Was researched in high concentration KCl solution and H2S／C02 coexistent system．The influence of temperature，salt concentration and other factors on corrosion of different species of steel was analyzed and synergistic inhibition effect between sodium silicate and acrylamide Was studied in high concentration KCl solution．While in H2S／C02 coexistent system，the relationship between corrosion inhibition efficiency and surface activity of three kinds of cationic surfactants，namely dodecyl trimethyl ammonium bromide(DTAB)，tetradecyl III 万方数据 万方数据 万方数据 北京化工大学硕士学位论文trimethyl 北京化工大学硕士学位论文 trimethyl ammonium bromide(TTAB)and cetyl trimethyl ammonium bromide(CTAB)，was studied．The synergistic inhibition effect between pyridinium salt(PB)and three kinds of cationic surfactants was also explored． The main research results are listed as follows： 1．High concentration KCl solu