铅同位素示踪在大气降尘重金属污染来源解析中的应用-NSFC.pdf

铅同位素示踪在大气降尘重金属污染来源解析中的应用* 1，2* 1 1 1 1 1 胡恭任 ，于瑞莲 ，胡起超 ，温先华 ，刘贤荣 ，张希琳 (1.华侨大学环境科学与工程系，厦门 361021；2.东华理工大学核资源与环境教育部重点实验室，南昌 330013) 摘要:为了分析大气降尘中铅的污染来源，解析各污染源对大气降尘铅的相对贡献值，在厦门市不同功能区采集了29 个大气降尘样品。用热电质谱 206 207 仪测定了大气降尘的总铅同位素组成，用ICP-MS 测定样品酸可溶相铅同位素组成。结果表明，厦门市大气降尘铅同位素 Pb/ Pb 比值变化较大为 206 207 206 207 1.1119~ 1.1738 。酸可溶相铅 Pb/ Pb 比值与福建土壤残渣相 Pb/ Pb 比值相差较大，表明厦门市大气降尘受到人类活动来来源铅的影响较大。 206 207 206 207 酸可溶相铅 Pb/ Pb 比值明显小于总量铅 Pb/ Pb 比值。铅同位素示踪表明厦门市大气降尘铅主要来源是燃煤，其次是自然源和汽车尾气。三 元混合模型分析燃煤、自然来源、汽车尾气对厦门市大气降尘总量铅的贡献率分别为48.57%、20.29%、31.14% 。 关键词：大气降尘；铅同位素；来源分析；厦门市 中图分类号：X823 文献标识码：A 文章编号： Application of stable lead isotope in tracing heavy metal sources in the atmospheric dustfall 1，2* 1 1 1 1 1 HU Gong-ren , YU Rui-lian , WEN Xian-hua , HU Qi-chao , LIU Xian-rong , ZHANG Xi-lin (1.College of Chemical Engineering, Huaqiao University, Xiamen 361021, China ；2. Key Laboratory of Nuclear Resources and Environment, Ministry of Education, East China University of Technology, Nanchang 330013, China) Abstract: To identify the sources of atmospheric dustfall, as well as to affirm the contribution rate of each source to such dustfall. Based on different areas of Xiamen city, we have obtained 29 atmospheric dustfall and 1 coal ash in a coal pile. Total Pb isotopic composition of each sample was analyzed by thermal mass spectrometry, while Pb isotopic ratios of acid soluble was determined by ICP-MS. The results in