6_新型固体聚羧酸高效减水剂的研制.pdfVIP

新型固体聚羧酸高效减水剂的研制 张智 雷宇芳鄢佳佳 李顺凯 屠柳青 （中交武汉港湾工程设计研究院有限公司武汉 430040 ） 摘 要：聚羧酸高效减水剂生产浓度一般为20～40%，不宜储存和运输，限制了其更广泛的 应用。本文利用本体聚合方法合成固体聚羧酸减水剂，即在不加任何溶剂的情况下，利用原 料中大单体 TPEG、丙烯酸的物理化学特性，通过合适的引发剂 （BPO ），实现反应原料熔 融态下的聚合反应。本文对本体聚合的反应条件进行了讨论和分析，最终确定了原料配比为 TPEG ：AA ：MAS = 0.8: 3.25 : 0.4 （摩尔比），引发剂BPO 用量为单体总质量的 1%，反 应温度为 80℃，引发剂滴加时间为2h ，保温时间为1.5h 的反应条件。反应结束后趁热将产 物倒出，冷却至室温，经研磨成粉末，得到产品。本文得到的固体聚羧酸减水剂产品经研磨 后无粘结现象，颗粒尺寸在0.125mm 时，46s 即可实现完全溶解，150 天未出现变质结块现 象。通过净浆试验和混凝土试验对产品进行了性能测试，测试结果表明，本文得到的产品性 能超过了国内同类固体聚羧酸高效减水剂的产品水平，达到了液体聚羧酸高效减水剂的技 术要求。就国内生产粉体产品技术而言，本体聚合法制备固体聚羧酸高效减水剂工艺简单， 操作容易，对环境友好，具有非常广阔的工业前景。 关键字：聚羧酸高效减水剂；固态；本体聚合 The Synthesis of Novel Solid Poly-carboxylic Water-reducer Zhang Zhi ，Lei Yu-fang jia ，Yan Jia-jia ， Li Shun-kai ， TU Liu-qing (Wuhan Harbour Engineering Design Research Institute Co.,Ltd of CCCG, Wuhan , 430071, China) Abstract: Poly-carboxylic acid high efficiency water reducing agent as a kind of new building materials, is usually 20 ~ 40% concentration, which was unfavorable for storage and transportation, and limited its more extensive application. In this work the solid poly-carboxylic acid water reducing agent was synthesized through bulk polymerization method without any solvent, in the presence of initiator (BPO), polymerized under the melting state. The reaction condition was selected after discussing and analyzing of the bulk polymerization. The molar ratio of crude materials was TPEG ：AA ：MAS = 0.8 : 3.25 : 0.4. The dosage of initiator (BPO) was 1% of the weight of the monomer. The temperature of the reaction was 80℃. The time of initiator dropwising was 2 hous and the time of warm keeping was 1.5 hours. The crude product was poured out before cool down after reaction. When cooled to room temperature, the end product was made after grinding as a powder. The powder of solid poly-carboxy