聚吡咯的制备及其於固态染料敏化太阳能电池特性之研究.docVIP

中文摘要 本論文主要是以DBSA 為乳化劑及摻雜劑，藉由乳化聚合法製備 可溶性之導電性聚吡咯(DBSA-PPy)以做為電洞傳輸材料，並構裝成全 固態TiO2/Dye/DBSA-PPy 太陽能電池。同時利用傅立葉轉換紅外線光 譜儀、紫外光可見光譜儀、X 光繞射儀、光電子光譜儀、掃描式電子 顯微鏡、表面分析-電子能譜儀、霍爾效應量測系統與太陽能模擬器等 之分析，系統化探討DBSA-PPy 分子形態與添加劑等對全固態 TiO2/Dye/DBSA-PPy 太陽能電池光伏特性與光電轉換效率(η)之影響及 其相互間之關係。由電壓-電流特性曲線結果顯示，PPy 分子骨幹排列 對全固態 TiO2/Dye/DBSA-PPy 太陽能電池光電特性有極為顯著的影 響。於DBSA-PPy 中，添加Zn(DBS)2 分散劑時，會因PPy 分子鏈的展 開，使電洞遷移率由0.6385 增加至0.8821 cm2/Vs，導致全固態 TiO2/Dye/DBSA-PPy-Zn(DBS)2 太陽能電池η 明顯的增加； 於 DBSA-PPy-Zn(DBS)2 中，若添加tBP 與LiI，Voc 與Jsc 值會因載子再 結合率下降及傳導帶電子在相鄰或不相鄰TiO2 間傳輸阻力與距離的降 低而明顯的增加，進而提昇TiO2/Dye/DBSA-PPy-Zn(DBS)2-tBP-LiI 太 陽能電池之η 增加。 於tBP (1 wt%)和LiI(0.1 M)添加量時，全固態 TiO2/Dye/DBSA-PPy-Zn(DBS)2-tBP-LiI 太陽能電池之η 增加至0.3434 %。 英文摘要 The conducting DBSA doped-polypyrrole (DBSA-PPy) composites were synthesized by using emulsion polymerization, where pyrrole and DBSA act as monomer and emulsifier/dopant, respectively. The solid-state TiO2/Dye/DBSA-PPy solar cells were fabricated by the sandwich technique, where the available commercially porous nano-TiO2, N3 derivative and the DBSA-PPy composites act as photoelectrode, dye and the hole transport material, respectively. When Zn(DBS)2 was added into DBSA-PPy composites, the DBSA-PPy backbone showed an unfold conformation, a red shift phenomenon in the UV-Vis spectra was observed. As compared with DBSA-PPy composites, the hole mobility in DBSA-PPy-Zn(DBS)2 composites is significantly increased from 0.6385 to 0.8821 cm2/Vs, leading to the increase in 　. As for I-V characteristics measurements, values of Voc and Jsc of the solid-state TiO2/Dye/DBSA-PPy-Zn(DBS)2-tBP-LiI solar cells are markedly improved, which is attributed to the reduction of the recombination rate of carrier and transition resistance of electron in TiO2. At 1wt% tBP and 0.1M LiI, the of TiO2/Dye/DBSA-PPy-Zn(DBS)2-tBP-LiI solar cell is about 0.3434 %. 目錄 摘要................................................................................................................I ABSTRACT........................................